ChemInform Abstract: Asymmetric 1,4-Addition of Arylboronic Acids to 2,3-Dihydro-4-pyridones Catalyzed by Axially Chiral NHC-Pd(II) Complexes.

ChemInform ◽  
2010 ◽  
Vol 41 (41) ◽  
pp. no-no
Author(s):  
Qin Xu ◽  
Rui Zhang ◽  
Tao Zhang ◽  
Min Shi
Keyword(s):  
Arylboronic Acids ◽  
Axially Chiral

Rhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides: Asymmetric Synthesis of Axially Chiral Allenylsilanes

2010 ◽  
Vol 132 (37) ◽  
pp. 12865-12867 ◽  
Author(s):  
Takahiro Nishimura ◽  
Hiroki Makino ◽  
Makoto Nagaosa ◽  
Tamio Hayashi
Keyword(s):  
Asymmetric Synthesis ◽  
Arylboronic Acids ◽  
Axially Chiral

Asymmetric Suzuki–Miyaura cross-coupling of 1-bromo-2-naphthoates using the helically chiral polymer ligand PQXphos

2015 ◽  
Vol 51 (33) ◽  
pp. 7211-7214 ◽  
Author(s):  
Yuto Akai ◽  
Laure Konnert ◽  
Takeshi Yamamoto ◽  
Michinori Suginome
Keyword(s):  
Cross Coupling ◽  
Arylboronic Acids ◽  
Helical Polymer ◽  
Axially Chiral ◽  
Chiral Polymer ◽  
Polymer Ligand ◽  
Polymer Ligands

Axially chiral 1,1′-biaryl-2-carboxylates were synthesized via Suzuki–Miyaura cross-coupling of 2,4-dimethylpentan-3-yl 1-halo-2-naphthoates with arylboronic acids with single-handed helical polymer ligands PQXphos.

Enantioselective palladium-catalyzed arylation of N-tosylarylimines with arylboronic acids using a chiral 2,2′-bipyridine ligand

2016 ◽  
Vol 14 (1) ◽  
pp. 55-58 ◽  
Author(s):  
Xiang Gao ◽  
Bo Wu ◽  
Zhong Yan ◽  
Yong-Gui Zhou
Keyword(s):  
Arylboronic Acids ◽  
Axially Chiral ◽  
Palladium Catalyzed ◽  
Bipyridine Ligand

An enantioselective palladium-catalyzed arylation of N-tosylarylimines with arylboronic acids was developed by using an axially chiral 2,2′-bipyridine ligand C3-ACBP, affording chiral diarylmethamines with up to 94% ee under exogenous-base-free conditions.

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