ChemInform Abstract: A Highly Versatile Catalyst System for the Cross-Coupling of Aryl Chlorides and Amines.

ChemInform ◽  
2010 ◽  
Vol 41 (23) ◽  
pp. no-no
Author(s):  
Rylan J. Lundgren ◽  
Antonia Sappong-Kumankumah ◽  
Mark Stradiotto
Keyword(s):  
Cross Coupling ◽  
Catalyst System ◽  
Aryl Chlorides ◽  
The Cross

A Highly Versatile Catalyst System for the Cross-Coupling of Aryl Chlorides and Amines

2010 ◽  
Vol 16 (6) ◽  
pp. 1983-1991 ◽  
Author(s):  
Rylan J. Lundgren ◽  
Antonia Sappong-Kumankumah ◽  
Mark Stradiotto
Keyword(s):  
Cross Coupling ◽  
Catalyst System ◽  
Aryl Chlorides ◽  
The Cross

scholarly journals A convenient catalyst system for microwave accelerated cross-coupling of a range of aryl boronic acids with aryl chlorides

2007 ◽  
Vol 3 ◽  
Author(s):  
Matthew L Clarke ◽  
Marcia B France ◽  
Jose A Fuentes ◽  
Edward J Milton ◽  
Geoffrey J Roff
Keyword(s):  
Cross Coupling ◽  
Catalyst System ◽  
Boronic Acids ◽  
Aryl Chlorides

Highly Active [Pd(μ-Cl)(Cl)(NHC)]2(NHC = N-Heterocyclic Carbene) in the Cross-Coupling of Grignard Reagents with Aryl Chlorides

2009 ◽  
Vol 28 (9) ◽  
pp. 2915-2919 ◽  
Author(s):  
Caroline E. Hartmann ◽  
Steven P. Nolan ◽  
Catherine S. J. Cazin
Keyword(s):  
Cross Coupling ◽  
Grignard Reagents ◽  
Aryl Chlorides ◽  
Highly Active ◽  
The Cross

Iron(ii) triflate/N-heterocyclic carbene-catalysed cross-coupling of arylmagnesiums with aryl chlorides and tosylates

2016 ◽  
Vol 52 (7) ◽  
pp. 1466-1469 ◽  
Author(s):  
Yi-Yuan Chua ◽  
Hung A. Duong
Keyword(s):  
High Efficiency ◽  
Cross Coupling ◽  
Catalyst System ◽  
Aryl Chlorides

An iron(ii) triflate/N-heterocyclic carbene catalyst system enables the coupling of arylmagnesiums with aryl chlorides and tosylates with high efficiency.

Thieme Chemistry Journals Awardees – Where Are They Now? Efficient Cross-Coupling of Secondary Amines/Azoles and Activated (Hetero)Aryl Chlorides Using an Air-Stable DPEPhos/Nickel Pre-Catalyst

Synlett ◽  
2017 ◽  
Vol 28 (13) ◽  
pp. 1586-1591 ◽  
Author(s):  
Mark Stradiotto ◽  
Ryan Sawatzky ◽  
Michael Ferguson
Keyword(s):  
Cross Coupling ◽  
Nickel Catalysts ◽  
Secondary Amines ◽  
Synthesis And Characterization ◽  
Aryl Chlorides ◽  
The Cross

Synthesis and characterization of the new air-stable pre-catalyst (DPEPhos)Ni(2-mesityl)Br (C1) is reported, along with the application of this pre-catalyst in the cross-coupling of secondary amines/azoles with activated (hetero)aryl chlorides to afford tertiary (hetero)anilines. The performance of C1 in these cross-couplings is competitive with some of the best and/or most widely employed nickel catalysts for such transformations.

Nickel-Catalyzed Cross-Coupling of Ammonia or Primary Alkylamines with (Hetero)aryl Sulfamates, Carbamates, or Pivalates

Synlett ◽  
2017 ◽  
Vol 28 (13) ◽  
pp. 1652-1656 ◽  
Author(s):  
Mark Stradiotto ◽  
Preston MacQueen
Keyword(s):  
Broad Spectrum ◽  
Room Temperature ◽  
Cross Coupling ◽  
Catalyst System ◽  
Boronate Ester ◽  
The Cross ◽  
First Time

A catalyst system capable of effecting the cross-coupling of ammonia or primary alkylamines with (hetero)aryl sulfamates, carbamates, or pivalates is reported for the first time. The air-stable nickel(II) pre-catalyst C1 tolerates a broad spectrum of heterocyclic functionality within both reaction partners, as well as ether, nitrile, pyrrole, trifluoromethyl, and boronate ester substituents. In the case of reactions involving primary alkylamines and (hetero)aryl sulfamates and carbamates, room-temperature cross-couplings were achieved.

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