ChemInform Abstract: Recent Advances for Controlling the Activity and the Recoverability of Hoveyda-Grubbs-Type Olefin Metathesis Catalysts

ChemInform ◽  
2010 ◽  
Vol 41 (10) ◽  
Author(s):  
Etienne Borre ◽  
Frederic Caijo ◽  
Diane Rix ◽  
Christophe Crevisy ◽  
Marc Mauduit
Keyword(s):  
Olefin Metathesis ◽  
Recent Advances ◽  
Metathesis Catalysts

scholarly journals Recent advances in ruthenium-based olefin metathesis

2018 ◽  
Vol 47 (12) ◽  
pp. 4510-4544 ◽  
Author(s):  
O. M. Ogba ◽  
N. C. Warner ◽  
D. J. O’Leary ◽  
R. H. Grubbs
Keyword(s):  
Organic Synthesis ◽  
Olefin Metathesis ◽  
Functional Group ◽  
Polymer Science ◽  
Enabling Technology ◽  
Broad Applicability ◽  
Recent Advances ◽  
Metathesis Catalysts

Ruthenium-based olefin metathesis catalysts, known for their functional group tolerance and broad applicability in organic synthesis and polymer science, continue to evolve as an enabling technology in these areas.

Activated Hoveyda‐Grubbs Olefin Metathesis Catalysts Derived from a Large Scale Produced Pharmaceutical Intermediate—Sildenafil Aldehyde

2021 ◽  
Author(s):  
Louis Monsigny ◽  
Jakub Piątkowski ◽  
Damian Trzybiński ◽  
Krzysztof Wozniak ◽  
Tomasz Nienałtowski ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Large Scale ◽  
Metathesis Catalysts

Nitrenium ions and trivalent boron ligands as analogues of N-heterocyclic carbenes in olefin metathesis: a computational study

2015 ◽  
Vol 44 (46) ◽  
pp. 20021-20026 ◽  
Author(s):  
A. Pazio ◽  
K. Woźniak ◽  
K. Grela ◽  
B. Trzaskowski
Keyword(s):  
Olefin Metathesis ◽  
Computational Study ◽  
Heterocyclic Carbenes ◽  
Mechanistic Study ◽  
Nitrenium Ions ◽  
Nitrenium Ion ◽  
Metathesis Catalysts

A DFT mechanistic study reveals that nitrenium ion-modified Hoveyda-like complexes are good candidates for latent metathesis catalysts, while boron-modified systems are candidates for very fast metathesis catalysts.

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