ChemInform Abstract: A Rapid and Green Approach to Chiral α-Hydroxy Esters: Asymmetric Transfer Hydrogenation (ATH) of α-Keto Esters in Water by Use of Surfactants.

ChemInform ◽  
2010 ◽  
Vol 41 (8) ◽  
Author(s):  
Lu Yin ◽  
Xian Jia ◽  
Xingshu Li ◽  
Albert S. C. Chan
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Keto Esters ◽  
Green Approach ◽  
Hydroxy Esters

Rhodium-mediated asymmetric transfer hydrogenation: a diastereo- and enantioselective synthesis of syn-α-amido β-hydroxy esters

2018 ◽  
Vol 54 (3) ◽  
pp. 283-286 ◽  
Author(s):  
Long-Sheng Zheng ◽  
Charlène Férard ◽  
Phannarath Phansavath ◽  
Virginie Ratovelomanana-Vidal
Keyword(s):  
Enantioselective Synthesis ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Keto Esters ◽  
Ru Complex ◽  
Efficient Access ◽  
Hydroxy Esters

The use of a Rh- instead of a Ru-complex in the asymmetric transfer hydrogenation of α-benzoylamino β-keto esters allowed a reversal of diastereoselectivity and an efficient access to a variety of syn α-amido β-hydroxy esters.

Dual Pathway for the Asymmetric Transfer Hydrogenation of α-Ketoimides to Chiral α-Hydroxy Imides or Chiral α-Hydroxy Esters

ChemCatChem ◽  
2015 ◽  
Vol 8 (2) ◽  
pp. 412-416 ◽  
Author(s):  
Qiankun Zhao ◽  
Yuxi Zhao ◽  
Hang Liao ◽  
Tanyu Cheng ◽  
Guohua Liu
Keyword(s):  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Dual Pathway ◽  
Hydroxy Esters
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