ChemInform Abstract: Two-Step, One-Pot Ni-Catalyzed Neopentylglycolborylation and Complementary Pd/Ni-Catalyzed Cross-Coupling with Aryl Halides, Mesylates, and Tosylates.

ChemInform ◽  
2009 ◽  
Vol 40 (12) ◽  
Author(s):  
Daniela A. Wilson ◽  
Christopher J. Wilson ◽  
Brad M. Rosen ◽  
Virgil Percec
Keyword(s):  
Cross Coupling ◽  
Aryl Halides ◽  
One Pot

One-pot Synthesis of Dibenzofurans via SNAr and Subsequent Ligand-free Palladium-catalyzed Intramolecular Aryl-aryl Cross-coupling Reactions under Microwave Irradiation

2011 ◽  
Vol 66 (8) ◽  
pp. 833-836
Author(s):  
Zhiping Che ◽  
Hui Xu
Keyword(s):  
Microwave Irradiation ◽  
Cross Coupling ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
One Pot ◽  
One Pot Synthesis ◽  
Cross Coupling Reactions ◽  
Ligand Free ◽  
Palladium Catalyzed ◽  
Snar Reaction

An efficient one-pot synthesis of dibenzofurans, via SNAr reaction of aryl halides and ortho-bromophenols in the presence of anhydrous K2CO3 and subsequent ligand-free palladium-catalyzed intramolecular aryl-aryl cross-coupling cyclization under microwave irradiation, is described.

A facile and convenient sequential homobimetallic catalytic approach towards β-methylstyrenes. A one-pot Stille cross-coupling/isomerization strategy

2014 ◽  
Vol 12 (22) ◽  
pp. 3735-3743 ◽  
Author(s):  
Sebastián O. Simonetti ◽  
Enrique L. Larghi ◽  
Teodoro S. Kaufman
Keyword(s):  
Double Bond ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Aryl Halides ◽  
One Pot ◽  
Cross Coupling Reaction

A one-pot approach towards β-methylstyrenes is reported. The transformation involves a Stille cross-coupling reaction of aryl halides with allyltributylstannane, followed by an in situ Pd-catalyzed double bond conjugative migration.

Stannylation of Aryl Halides, Stille Cross-Coupling, and One-Pot, Two-Step Stannylation/Stille Cross-Coupling Reactions under Solvent-Free Conditions

2018 ◽  
Vol 2018 (1) ◽  
pp. 120-125 ◽  
Author(s):  
Pavel S. Gribanov ◽  
Yulia D. Golenko ◽  
Maxim A. Topchiy ◽  
Lidiya I. Minaeva ◽  
Andrey F. Asachenko ◽  
...  
Keyword(s):  
Cross Coupling ◽  
Solvent Free ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
One Pot ◽  
Cross Coupling Reactions ◽  
Solvent Free Conditions

Two-Step, One-Pot Ni-Catalyzed Neopentylglycolborylation and Complementary Pd/Ni-Catalyzed Cross-Coupling with Aryl Halides, Mesylates, and Tosylates

2008 ◽  
Vol 10 (21) ◽  
pp. 4879-4882 ◽  
Author(s):  
Daniela A. Wilson ◽  
Christopher J. Wilson ◽  
Brad M. Rosen ◽  
Virgil Percec
Keyword(s):  
Cross Coupling ◽  
Aryl Halides ◽  
One Pot

scholarly journals Clean and fast cross-coupling of aryl halides in one-pot

2014 ◽  
Vol 10 ◽  
pp. 897-901 ◽  
Author(s):  
Valerica Pandarus ◽  
Geneviève Gingras ◽  
François Béland ◽  
Rosaria Ciriminna ◽  
Mario Pagliaro
Keyword(s):  
Cross Coupling ◽  
Aryl Halides ◽  
Environmental Benefits ◽  
High Yield ◽  
Pd Catalyst ◽  
Synthetic Methodology ◽  
One Pot ◽  
Aryl Bromides

Unsymmetrically coupled biaryls are synthesized in high yield starting from different aryl bromides and bis(pinacolato)diboron by carrying out the Miyaura borylation reaction followed by the Suzuki–Miyaura reaction in the same reaction pot over 1–2 mol % SiliaCat DPP-Pd. The SiliaCat DPP-Pd catalyst is air-stable and the method does not require the use of inert conditions. The use of non-toxic isopropanol or 2-butanol as reaction solvent further adds to the environmental benefits of this new green synthetic methodology.

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