ChemInform Abstract: An Investigation into the Allylic Imidate Rearrangement of Trichloroacetimidates Catalyzed by Cobalt Oxazoline Palladacycles.

ChemInform ◽  
2008 ◽  
Vol 39 (18) ◽  
Author(s):  
Hiroshi Nomura ◽  
Christopher J. Richards
Keyword(s):  
Allylic Imidate

ChemInform Abstract: Allylic Imidate Rearrangements Catalyzed by Planar Chiral Palladacycles

ChemInform ◽  
2010 ◽  
Vol 41 (45) ◽  
pp. no-no
Author(s):  
Hiroshi Nomura ◽  
Christopher J. Richards
Keyword(s):  
Allylic Imidate

Palladium-Catalyzed [1,3]-O-to-N Rearrangement of Allylic ­Imidates

Synlett ◽  
2021 ◽  
Author(s):  
Yusuke Kuroda
Keyword(s):  
Oxidative Addition ◽  
Allylic Amines ◽  
Palladium Catalyzed ◽  
Allylic Imidate ◽  
Novel Strategy

AbstractThe rearrangement of allylic imidates is a powerful transformation for the synthesis of allylic amines. Whereas the [3,3]-rearrangement has long been established as the Overman rearrangement, the corresponding [1,3]-rearrangement is rare. Here, we report a novel strategy for the [1,3]-rearrangement of imidates based on the oxidative addition of a palladium(0) catalyst to an allylic imidate. Structurally distinct allylic amides could be synthesized under mild and base-free conditions.

Allylic Imidate Rearrangements Catalyzed by Planar Chiral Palladacycles

2010 ◽  
Vol 5 (8) ◽  
pp. 1726-1740 ◽  
Author(s):  
Hiroshi Nomura ◽  
Christopher J. Richards
Keyword(s):  
Allylic Imidate

Factors affecting the regioselection of allylic imidate iodocyclization

1986 ◽  
Vol 51 (25) ◽  
pp. 4905-4910 ◽  
Author(s):  
Alessandro Bongini ◽  
Giuliana Cardillo ◽  
Mario Orena ◽  
Sergio Sandri ◽  
Claudia Tomasini
Keyword(s):  
Factors Affecting ◽  
Allylic Imidate

ChemInform Abstract: Enantioselective Synthesis and Application to the Allylic Imidate Rearrangement of Amine-Coordinated Palladacycle Catalysts of Cobalt Sandwich Complexes.

ChemInform ◽  
2014 ◽  
Vol 45 (22) ◽  
pp. no-no
Author(s):  
Doyle J. Cassar ◽  
Gennadiy Ilyashenko ◽  
Muhammad Ismail ◽  
James Woods ◽  
David L. Hughes ◽  
...  
Keyword(s):  
Enantioselective Synthesis ◽  
Sandwich Complexes ◽  
Allylic Imidate
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