ChemInform Abstract: Reactivity of Trihexyl(tetradecyl)phosphonium Chloride, a Room-Temperature Phosphonium Ionic Liquid.

ChemInform ◽  
2008 ◽  
Vol 39 (15) ◽  
Author(s):  
Ming-Chung Tseng ◽  
Huang-Chuan Kan ◽  
Yen-Ho Chu
Keyword(s):  
Ionic Liquid ◽  
Room Temperature ◽  
Phosphonium Chloride ◽  
Phosphonium Ionic Liquid

Directed nucleation of monomeric and dimeric uranium(vi) complexes with a room temperature carboxyl-functionalized phosphonium ionic liquid

2013 ◽  
Vol 49 (19) ◽  
pp. 1903 ◽  
Author(s):  
Xiao-Yan Chen ◽  
George S. Goff ◽  
Mauricio Quiroz-Guzman ◽  
Daniel P. Fagnant ◽  
Joan F. Brennecke ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Room Temperature ◽  
Phosphonium Ionic Liquid

A Lithium Battery Electrolyte Based on a Room-temperature Phosphonium Ionic Liquid

2008 ◽  
Vol 37 (3) ◽  
pp. 314-315 ◽  
Author(s):  
Katsuhiko Tsunashima ◽  
Fumihiro Yonekawa ◽  
Masashi Sugiya
Keyword(s):  
Ionic Liquid ◽  
Lithium Battery ◽  
Room Temperature ◽  
Phosphonium Ionic Liquid ◽  
Battery Electrolyte

Preparation and Characterization of a Novel Room Temperature Dicationic Ionic Liquid and its Application in the Synthesis of Xanthenediones Under Solvent-Free Conditions

2018 ◽  
Vol 21 (8) ◽  
pp. 602-608 ◽  
Author(s):  
Zainab Ehsani-Nasab ◽  
Ali Ezabadi
Keyword(s):  
Ionic Liquid ◽  
Room Temperature ◽  
Reaction Times ◽  
Significant Loss ◽  
Solvent Free ◽  
Acidity Function ◽  
Efficient Catalyst ◽  
Solvent Free Conditions ◽  
Hammett Acidity Function ◽  
Dicationic Ionic Liquid

Aim and Objective: In the present work, 1, 1’-sulfinyldiethylammonium bis (hydrogen sulfate) as a novel room temperature dicationic ionic liquid was synthesized and used as a catalyst for xanthenediones synthesis. Material and Method: The dicationic ionic liquid has been synthesized using ethylamine and thionyl chloride as precursors. Then, by the reaction of [(EtNH2)2SO]Cl2 with H2SO4, [(EtNH2)2SO][HSO4]2 was prepared and after that, it was characterized by FT-IR, 1H NMR, 13C NMR as well as Hammett acidity function. This dicationic ionic liquid was used as a catalyst for the synthesis of xanthenediones via condensation of structurally diverse aldehydes and dimedone under solvent-free conditions. The progress of the reaction was monitored by thin layer chromatography (ethyl acetate/n-hexane = 3/7). Results: An efficient solvent-free method for the synthesis of xanthenediones has been developed in the presence of [(EtNH2)2SO][HSO4]2 as a powerful catalyst with high to excellent yields, and short reaction times. Additionally, recycling studies have demonstrated that the dicationic ionic liquid can be readily recovered and reused at least four times without significant loss of its catalytic activity. Conclusion: This new dicationic ionic liquid can act as a highly efficient catalyst for xanthenediones synthesis under solvent-free conditions.

Phosphonium ionic liquid-based electrolyte for high voltage Li-ion batteries: Effect of ionic liquid ratio

2021 ◽  
Author(s):  
Yassine Bencherifi ◽  
Badre Larhrib ◽  
Adnan Sayegh ◽  
Georgios Nikiforidis ◽  
Mérièm Anouti
Keyword(s):  
Ionic Liquid ◽  
High Voltage ◽  
Li Ion Batteries ◽  
Liquid Ratio ◽  
Phosphonium Ionic Liquid ◽  
Li Ion

Long lifetime phosphorescence and X-ray scintillation of chlorobismuthate hybrids incorporating ionic liquid cations

2021 ◽  
Author(s):  
Jian-Ce Jin ◽  
Yang-Peng Lin ◽  
Yi-Heng Wu ◽  
Liaokuo Gong ◽  
Nan-Nan Shen ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Room Temperature ◽  
Room Temperature Phosphorescence ◽  
X Ray ◽  
Long Lifetime

Two chlorobismuthate hybrids incorportating ionic liquid cations (ILCs) with second-level room-temperature phosphorescence (RTP) were obtained, namely [Emim]BiCl4(bp2do) (1) and [Emmim]BiCl4(bp2do) (2) (Emim = 1-ethyl-3-methylimidazolium, Emmim = 1-ethyl-2,3-dimethylimidazolium, bp2do = 2,2'-bipyridyl-1,1'-dioxide)....

The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface

ChemPhysChem ◽  
2021 ◽  
Author(s):  
Marcin Wojciech Opallo ◽  
Justyna Kalisz ◽  
Wojciech Nogala ◽  
Wojciech Adamiak ◽  
Mateusz Gocyla ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solvent Effect ◽  
Liquid Water ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid ◽  
Water Interface ◽  
H2o2 Generation

Electrochemical Kinetics of Ag|Ag+and TMPD|TMPD+•in the Room-Temperature Ionic Liquid [C4mpyrr][NTf2]; toward Optimizing Reference Electrodes for Voltammetry in RTILs

2007 ◽  
Vol 111 (37) ◽  
pp. 13957-13966 ◽  
Author(s):  
Emma I. Rogers ◽  
Debbie S. Silvester ◽  
Sarah E. Ward Jones ◽  
Leigh Aldous ◽  
Christopher Hardacre ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Room Temperature ◽  
Room Temperature Ionic Liquid ◽  
Electrochemical Kinetics ◽  
Reference Electrodes ◽  
Kinetics Of
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