The Interactions Affecting Organic Reactivity and Selectivity in Ionic Liquids

ChemInform ◽  
2007 ◽  
Vol 38 (34) ◽  
Author(s):  
Cinzia Chiappe ◽  
Daniela Pieraccini ◽  
Christian Silvio Pomelli
Keyword(s):  
Ionic Liquids ◽  
Organic Reactivity

Organic Reactivity in Ionic Liquids: Some Mechanistic Insights into Nucleophilic Substitution Reactions

2005 ◽  
Vol 2005 (7) ◽  
pp. 413-417 ◽  
Author(s):  
N. Llewellyn Lancaster
Keyword(s):  
Ionic Liquids ◽  
Nucleophilic Substitution ◽  
Organic Reactions ◽  
Substitution Reactions ◽  
Nucleophilic Substitutions ◽  
Nucleophilic Substitution Reactions ◽  
Quantitative Studies ◽  
Alternative Solvents ◽  
Molecular Solvents ◽  
Organic Reactivity

Ionic liquids have been advanced as alternative solvents for organic reactions. In this paper, the principal findings of studies on nucleophilic substitutions in ionic liquids are reviewed. Thus our examination of halides (Cl-, Br- and I) in a range of ionic liquids is combined with our study of amine nucleophilicity into a single narrative. There have been a few other quantitative studies of nucleophilic substitutions in ionic liquids, and the results of these studies are also summarised in this work. These data are compared to related reactions in molecular solvents, and used to show where ionic liquids do (and do not) offer advantages over molecular solvents for nucleophilic substitutions.

Ionic liquids: solvent properties and organic reactivity

2005 ◽  
Vol 18 (4) ◽  
pp. 275-297 ◽  
Author(s):  
Cinzia Chiappe ◽  
Daniela Pieraccini
Keyword(s):  
Ionic Liquids ◽  
Solvent Properties ◽  
Organic Reactivity

Ionic Liquids: Solvent Properties and Organic Reactivity

ChemInform ◽  
2005 ◽  
Vol 36 (33) ◽  
Author(s):  
Cinzia Chiappe ◽  
Daniela Pieraccini
Keyword(s):  
Ionic Liquids ◽  
Solvent Properties ◽  
Organic Reactivity

Ionic liquids: “normal” solvents or nanostructured fluids?

2021 ◽  
Vol 19 (10) ◽  
pp. 2076-2095
Author(s):  
Salvatore Marullo ◽  
Francesca D'Anna ◽  
Carla Rizzo ◽  
Floriana Billeci
Keyword(s):  
Ionic Liquids ◽  
Solvation Energy ◽  
Linear Solvation Energy Relationships ◽  
Energy Relationships ◽  
Linear Solvation Energy ◽  
Linear Solvation ◽  
Organic Reactivity

This review provides an overview of the literature from 2010 to the present day, covering the effect of ionic liquids (ILs) on organic reactivity. Two major viewpoints emerge, based on linear solvation energy relationships or nanostructure of ILs.

Structural features of ionic liquids: consequences for material preparation and organic reactivity

2013 ◽  
Vol 15 (10) ◽  
pp. 2655 ◽  
Author(s):  
Cameron C. Weber ◽  
Anthony F. Masters ◽  
Thomas Maschmeyer
Keyword(s):  
Ionic Liquids ◽  
Structural Features ◽  
Material Preparation ◽  
Organic Reactivity
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