A Chiral Phosphepine—Olefin Rhodium Complex as an Efficient Catalyst for the Asymmetric Conjugate Addition.

ChemInform ◽  
2007 ◽  
Vol 38 (19) ◽  
Author(s):  
Peter Kasak ◽  
Vladimir B. Arion ◽  
Michael Widhalm
2017 ◽  
Vol 53 (54) ◽  
pp. 7665-7668 ◽  
Author(s):  
Shao-Xia Lin ◽  
Gui-Jun Sun ◽  
Qiang Kang

An efficient enantioselective conjugate addition of photogenerated α-amino radicals to Michael acceptors catalyzed by a single and newly prepared chiral-at-metal rhodium complex was established.


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