Double Catalytic Enantioselective Michael Addition Reactions of Tertiary Nucleophile Precursors — Tertiary/Quaternary and Quaternary/Quaternary Carbon—Carbon Bond Formations.

ChemInform ◽  
2007 ◽  
Vol 38 (14) ◽  
Author(s):  
Hiroshi Yanagita ◽  
Kazuhiro Kodama ◽  
Shuji Kanemasa
Keyword(s):  
Michael Addition ◽  
Addition Reactions ◽  
Quaternary Carbon ◽  
Carbon Bond ◽  
Carbon Carbon Bond

Ready Carbon-Carbon Bond Formation of 2-(Trifluoromethyl)acrylate via Michael Addition Reactions

1994 ◽  
Vol 59 (17) ◽  
pp. 5100-5103 ◽  
Author(s):  
Takashi Yamazaki ◽  
Shuichi Hiraoka ◽  
Tomoya Kitazume
Keyword(s):  
Michael Addition ◽  
Bond Formation ◽  
Addition Reactions ◽  
Carbon Bond ◽  
Carbon Carbon Bond

scholarly journals Conjugated nitrosoalkenes as Michael acceptors in carbon–carbon bond forming reactions: a review and perspective

2017 ◽  
Vol 13 ◽  
pp. 2214-2234 ◽  
Author(s):  
Yaroslav Dmitrievich Boyko ◽  
Valentin Sergeevich Dorokhov ◽  
Alexey Yu Sukhorukov ◽  
Sema Leibovich Ioffe
Keyword(s):  
Total Synthesis ◽  
Organic Synthesis ◽  
Michael Addition ◽  
High Reactivity ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Recent Developments ◽  
Michael Acceptors

Despite of their chemical instability and high reactivity, conjugated nitrosoalkenes are useful intermediates in target-oriented organic synthesis. The present review deals with carbon–carbon bond forming reactions involving Michael addition to α-nitrosoalkenes with a particular focus on recent developments in this methodology and its use in total synthesis.

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