Organic Chemistry for Inorganic Chemists: Unsymmetrical Schiff Bases Derived from 3-Formylsalicylic Acid as Versatile Ligands in Coordination Chemistry

ChemInform ◽  
2007 ◽  
Vol 38 (9) ◽  
Author(s):  
Marius Andruh ◽  
Floriana Tuna
Keyword(s):  
Organic Chemistry ◽  
Coordination Chemistry ◽  
Schiff Bases

Carbohydrazide analogues: a review of synthesis and biological activities

2021 ◽  
Vol 21 ◽  
Author(s):  
Ebuka Leonard Onyeyilim ◽  
Mercy Amarachi Ezeokonkwo ◽  
David Izuchukwu Ugwu ◽  
Chiamaka Peace Uzoewulu ◽  
Florence Uchenna Eze ◽  
...  
Keyword(s):  
Organic Chemistry ◽  
Inorganic Chemistry ◽  
Schiff Bases ◽  
Bioactive Compounds ◽  
Biological Activities ◽  
Structure Activity Relationship ◽  
Activity Relationship ◽  
Important Class ◽  
Synthetic Route ◽  
Structure Activity

: Carbohydrazides and their Schiff bases are important class of heterocycles that are not only employed in the area of organic chemistry, but also have tremendous applications in physical and inorganic chemistry. A series of potential bioactive compounds, containing carbohydrazide functionality and their hydrazone derivatives have been synthesized and screened for antibacterial, anticancer, antifungal and anti-inflammatory etc. This brief review discloses some synthetic route to so many reported carbohydrazides, their Schiff bases, their biological activities and their structure activity relationship.

scholarly journals When Stereochemistry Raised Its Ugly Head in Coordination Chemistry—An Appreciation of Howard Flack

Chemistry ◽  
2020 ◽  
Vol 2 (3) ◽  
pp. 759-776
Author(s):  
Edwin C. Constable ◽  
Catherine E. Housecroft
Keyword(s):  
Organic Chemistry ◽  
Coordination Chemistry ◽  
Absolute Configuration ◽  
Coordination Compounds ◽  
Routine Method ◽  
Absolute Determination ◽  
Chiral Compounds ◽  
The Absolute

Chiral compounds have played an important role in the development of coordination chemistry. Unlike organic chemistry, where mechanistic rules allowed the establishment of absolute configurations for numerous compounds once a single absolute determination had been made, coordination compounds are more complex. This article discusses the development of crystallographic methods and the interplay with coordination chemistry. Most importantly, the development of the Flack parameter is identified as providing a routine method for determining the absolute configuration of coordination compounds.

Synthesis, Characterization and Coordination Chemistry of Some Selenium-Containing Macrocyclic Schiff Bases

2005 ◽  
Vol 2005 (6) ◽  
pp. 1114-1126 ◽  
Author(s):  
Arunashree Panda ◽  
Saija C. Menon ◽  
Harkesh B. Singh ◽  
Christopher P. Morley ◽  
Robert Bachman ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Schiff Bases

First use of the maleamate(−1) ligand in coordination chemistry: Dinuclear copper(II) complexes with N-donors and their interesting ‘organic’ chemistry

2007 ◽  
Vol 10 (3) ◽  
pp. 318-323 ◽  
Author(s):  
Katerina N. Lazarou ◽  
Iordanis Chadjistamatis ◽  
Vassilis Psycharis ◽  
Spyros P. Perlepes ◽  
Catherine P. Raptopoulou
Keyword(s):  
Organic Chemistry ◽  
Coordination Chemistry ◽  
Dinuclear Copper

Amalgamation and Scrutinizing of Leucine Derivatives Schiff bases Complexes as Antimicrobial Agent

2021 ◽  
Vol 25 ◽  
Author(s):  
Muhammad Pervaiz ◽  
Ikram Ahmad ◽  
Zohaib Saeed ◽  
Muhammad Sagir ◽  
Umer Younas ◽  
...  
Keyword(s):  
Amino Acids ◽  
Coordination Chemistry ◽  
Metal Complexes ◽  
Schiff Bases ◽  
Condensation Reaction ◽  
Amino Acid Derivatives ◽  
Comprehensive Review ◽  
Antimicrobial Potential ◽  
Donor Ability ◽  
Derivatives Of

: The enhanced applications of Schiff bases metal complexes of amino acid derivatives have captured the attention of researchers for the synthesis of leucine derivatives of Schiff bases metal complexes. Amino acids are considered to be essential part of food supplements as well as derivatives of Schiff bases in coordination chemistry due to their donor ability. The leucine derivatives Schiff bases ligand have been synthesized by condensation reaction between amine of leucine with aldehyde or ketone bearing molecules attached with them. These complexes were characterized by different spectroscopic tools in order to confirm their structural geometries. The structural geometries are considered to be very important in order to improve the antimicrobial potential of leucine derivative metal complexes. By taking into account the antimicrobial potential of titled compounds, a comprehensive review of leucine derivatives of Schiff bases metal complexes has been compiled.

Nomenclature of Organometallic Compounds of the Transition Elements (IUPAC Recommendations 1999)

1999 ◽  
Vol 71 (8) ◽  
pp. 1557-1585 ◽  
Author(s):  
A. Salzer
Keyword(s):  
Organic Chemistry ◽  
Coordination Chemistry ◽  
Valence Electron ◽  
Organic Ligand ◽  
Organometallic Compounds ◽  
Central Metal Atom ◽  
Central Metal ◽  
Transition Elements ◽  
Multiple Bonds ◽  
Single Bonds

Organometallic compounds are defined as containing at least one metal-carbon bond between an organic molecule, ion, or radical and a metal. Organometallic nomenclature therefore usually combines the nomenclature of organic chemisty and that of coordination chemistry. Provisional rules outlining nomenclature for such compounds are found both in Nomenclature of Organic Chemistry, 1979 and in Nomenclature of Inorganic Chemistry, 1990This document describes the nomenclature for organometallic compounds of the transition elements, that is compounds with metal-carbon single bonds, metal-carbon multiple bonds as well as complexes with unsaturated molecules (metal-p-complexes).Organometallic compounds are considered to be produced by addition reactions and so they are named on an addition principle. The name therefore is built around the central metal atom name. Organic ligand names are derived according to the rules of organic chemistry with appropriate endings to indicate the different bonding modes. To designate the points of attachment of ligands in more complicated structures, the h, k, and m-notations are used. The final section deals with the abbreviated nomenclature for metallocenes and their derivatives.ContentsIntroduction Systems of Nomenclature2.1 Binary type nomenclature 2.2 Substitutive nomenlcature 2.3 Coordination nomenclature Coordination Nomenclature3.1 General definitions of coordination chemistry 3.2 Oxidation numbers and net charges 3.3 Formulae and names for coordination compounds Nomenclature for Organometallic Compounds of Transition Metals 4.1 Valence-electron-numbers and the 18-valence-electron-rule 4.2 Ligand names 4.2.1 Ligands coordinating by one metal-carbon single bond 4.2.2 Ligands coordinating by several metal-carbon single bonds 4.2.3 Ligands coordinating by metal-carbon multiple bonds 4.2.4 Complexes with unsaturated molecules or groups 4.3 Metallocene nomenclature

Sign in / Sign up

Export Citation Format

Share Document