Achiral Benzophenone Ligand—Rhodium Complex with Chiral Diamine Activator for High Enantiocontrol in Asymmetric Transfer Hydrogenation.

ChemInform ◽  
2006 ◽  
Vol 37 (41) ◽  
Author(s):  
Koichi Mikami ◽  
Kazuki Wakabayashi ◽  
Yukinori Yusa ◽  
Kohsuke Aikawa
Keyword(s):  
Transfer Hydrogenation ◽  
Rhodium Complex ◽  
Asymmetric Transfer Hydrogenation ◽  
Chiral Diamine

Rhodium-catalyzed asymmetric transfer hydrogenation of 4-quinolone derivatives

2020 ◽  
Vol 7 (8) ◽  
pp. 975-979 ◽  
Author(s):  
Bin He ◽  
Phannarath Phansavath ◽  
Virginie Ratovelomanana-Vidal
Keyword(s):  
Formic Acid ◽  
Transfer Hydrogenation ◽  
Rhodium Complex ◽  
Asymmetric Transfer Hydrogenation ◽  
Quinolone Derivatives

4-Quinolone derivatives were conveniently reduced to 1,2,3,4-tetrahydroquinoline-4-ols with excellent enantioselectivities through asymmetric transfer hydrogenation using a tethered rhodium complex and formic acid/triethylamine as the hydride source.

Asymmetric transfer hydrogenation of ketones and imines with novel water-soluble chiral diamine as ligand in neat water

2007 ◽  
Vol 9 (1) ◽  
pp. 23-25 ◽  
Author(s):  
Li Li ◽  
Jiashou Wu ◽  
Fei Wang ◽  
Jian Liao ◽  
Hua Zhang ◽  
...  
Keyword(s):  
Water Soluble ◽  
Transfer Hydrogenation ◽  
Asymmetric Transfer Hydrogenation ◽  
Chiral Diamine ◽  
Neat Water
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