Spedding Award Lecture. Exploratory Synthesis of Reduced Rare-Earth-Metal Halides, Chalcogenides, Intermetallics. New Compounds, Structures, and Properties

ChemInform ◽  
2006 ◽  
Vol 37 (35) ◽  
Author(s):  
John D. Corbett
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Metal Halides ◽  
Structures And Properties ◽  
New Compounds

scholarly journals Rare-Earth Metal-Rich Antimonides: Syntheses, Structures, and Properties of Tm3Sb and Lu7Sb3.

ChemInform ◽  
2007 ◽  
Vol 38 (23) ◽  
Author(s):  
Shalabh Gupta ◽  
Ling Chen ◽  
Ashok K. Ganguli ◽  
John D. Corbett
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Structures And Properties

ChemInform Abstract: Trends in Syntheses, Structures, and Properties for Three Series of Ammine Rare-Earth Metal Borohydrides, M(BH4)3·nNH3(M: Y, Gd, and Dy).

ChemInform ◽  
2015 ◽  
Vol 46 (41) ◽  
pp. no-no
Author(s):  
Lars H. Jepsen ◽  
Morten B. Ley ◽  
Cerny Radovan Cerny Radovan ◽  
Young-Su Lee ◽  
Young Whan Cho ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Structures And Properties

Synthese und Kristallstrukturen von Seltenerdmetall-Antimoniden des Palladiums / Synthesis and Crystal Structures of Antimonides of Rare-Earth Metals and Palladium

2006 ◽  
Vol 61 (1) ◽  
pp. 17-22 ◽  
Author(s):  
Anette Imre ◽  
Albrecht Mewis
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Three Dimensional ◽  
Earth Metal ◽  
Type Structure ◽  
X Ray ◽  
Metal Atoms ◽  
New Compounds ◽  
Ray Methods ◽  
The Rare Earth

The new compounds Pr3Pd6Sb5 (a = 13.442(3), b = 4.442(1), c = 9.994(2) Å ), Nd3Pd6Sb5 (a = 13.412(3), b = 4.431(1), c = 9.962(2) Å), and Gd3Pd6Sb5 (a = 13.293(2), b = 4.397(1), c = 9.881(2) Å) are isotypic and crystallize with the Ce3Pd6Sb5 type structure (Pmmn; Z = 2). The rare-earth metal atoms are arranged in form of three pseudo-body-centered subcells, whereas Pd and Sb atoms form a three-dimensional arrangement derived from the well-known ThCr2Si2 and CaBe2Ge2 structures. GdPdSb (a = 4.566(1), c = 7.444(1) Å) and DyPdSb (a = 4.545(1), c = 7.354(1) Å) crystallize with an ordered variant of the CaIn2 type structure (P63mc; Z = 2), also called as LiGaGe type, with slightly puckered hexagon nets of Pd and Sb atoms, which trigonally coordinate each other. In this series a decreasing radius of the rare-earth metal allows a tetrahedral non-metal environment of the Pd atoms and accordingly ScPdSb (a = 6.310(1) Å) forms the MgAgAs type structure (F4̄3m; Z = 4), a filled variant of the sphalerite type. The antimonides were prepared by heating mixtures of the elements at 600 °C and subsequent annealing at 900 - 1100 °C. Their structures have been determined by single-crystal X-ray methods.

Sign in / Sign up

Export Citation Format

Share Document