scholarly journals Importance of the O—M—O Bridges (M: V5+, Mo6+) for the Spin-Exchange Interactions in the Magnetic Oxides of Cu2+ Ions Bridged by MO4 Tetrahedra: Spin-Lattice Models of Rb2Cu2(MoO4)3, BaCu2V2O8, and KBa3Ca4Cu3V7O28.

ChemInform ◽  
2006 ◽  
Vol 37 (33) ◽  
Author(s):  
Hyun-Joo Koo ◽  
Myung-Hwan Whangbo
Keyword(s):  
Spin Exchange ◽  
Lattice Models ◽  
Exchange Interactions ◽  
Magnetic Oxides ◽  
Spin Lattice

scholarly journals Pressure-induced normal-incommensurate-commensurate phase transitions in TiPO4

2014 ◽  
Vol 70 (a1) ◽  
pp. C263-C263 ◽  
Author(s):  
Maxim Bykov ◽  
Elena Bykova ◽  
Leonid Dubrovinsky ◽  
Michael Hanfland ◽  
Hanns-Peter Liermann ◽  
...  
Keyword(s):  
High Pressure ◽  
Phase Transitions ◽  
Degrees Of Freedom ◽  
Spin Exchange ◽  
Exchange Interactions ◽  
Quantum Spin ◽  
Singlet Ground State ◽  
Transition Temperatures ◽  
Spin Lattice ◽  
Commensurate Phase

The complex interplay between spin, charge, orbital, and lattice degrees of freedom has made low-dimensional quantum spin magnets with strong antiferromagnetic (AF) spin-exchange coupling prime candidates for studying unusual magnetic phenomena. A progressive spin-lattice dimerization in one-dimensional AF Heisenberg chains, which occurs below a critical temperature and induces a singlet ground state with a magnetic gap, is commonly referred to as spin-Peierls (SP) transition. Recently, the compounds TiOX (X = Cl, Br) and TiPO4have been intensively investigated due to their unconventional behavior [1,2]. Unlike standard SP systems, TiOX and TiPO4undergo a sequence of normal-incommensurate-commensurate phase transitions on cooling at remarkably high transition temperatures. The transition temperatures are related to the direct exchange interactions between Ti ions, which increases strongly with decreasing the distance between the Ti ions, and therefore is very sensitive to the applied hydrostatic pressure. We have performed pressure-dependent single-crystal X-ray diffraction of TiPO4using synchrotron radiation. TiPO4undergoes a pressure-induced pahse transiton towards an incommensurate phase already below 10 GPa. This transformation is followed by the lock-in phase transition to the dimerized SP phase. Both structures are analogous to those at low temperatures, but reveal significantly larger modulation amplitudes. In this contribution we will present the detailed discussion of the high-pressure structures of TiPO4and their behavior on compression. Furthermore, similarities and differences of high-pressure phase diagrams of TiOCl and TiPO4and discrepancies between predicted and observed structures will be considered.

Spin exchange interactions in hexagonal manganites RMnO3 (R = Tb, Dy, Ho, Er) epitaxial thin films

2011 ◽  
Vol 99 (5) ◽  
pp. 052506 ◽  
Author(s):  
Xiang-Bai Chen ◽  
Nguyen Thi Minh Hien ◽  
D. Lee ◽  
S.-Y. Jang ◽  
T. W. Noh ◽  
...  
Keyword(s):  
Thin Films ◽  
Spin Exchange ◽  
Exchange Interactions ◽  
Epitaxial Thin Films ◽  
Hexagonal Manganites

scholarly journals Disentangling orbital and spin exchange interactions for Co2+ on a rocksalt lattice

2018 ◽  
Vol 98 (2) ◽  
Author(s):  
P. M. Sarte ◽  
R. A. Cowley ◽  
E. E. Rodriguez ◽  
E. Pachoud ◽  
D. Le ◽  
...  
Keyword(s):  
Spin Exchange ◽  
Exchange Interactions
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