Hetero-Diels—Alder Reaction Catalyzed by Self-Organized Polymeric Rare Earth Complexes under Solvent-Free Conditions.

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Grinding of various electron-deficient dienophiles with diverse dienes in a pestle and mortar for 1–15 minutes afforded the corresponding Diels–Alder adducts in quantitative yields under catalyst-free and solvent-free conditions, without the necessity for any purification steps.


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