New Rare-Earth Transition-Metal Intermetallic Compounds and Metastable Phases for Permanent Magnetic Materials

ChemInform ◽  
2006 ◽  
Vol 37 (15) ◽  
Author(s):  
Z. D. Zhang
ChemInform ◽  
2010 ◽  
Vol 33 (52) ◽  
pp. no-no
Author(s):  
R. J. Radwanski ◽  
R. Michalski ◽  
Z. Ropka ◽  
A. Blaut

1973 ◽  
Author(s):  
J. J. Becker ◽  
M. G. Benz ◽  
R. E. Cech ◽  
R. J. Charles ◽  
M. Doser

2008 ◽  
Vol 63 (9) ◽  
pp. 1127-1130 ◽  
Author(s):  
Falko M. Schappacher ◽  
Ute Ch. Rodewald ◽  
Rainer Pöttgen

New intermetallic compounds RE4TCd (RE = Y, La-Nd, Sm, Gd-Tm, Lu; T = Ni, Pd, Ir, Pt) were synthesized by melting of the elements in sealed tantalum tubes in a highfrequency furnace. They crystallize with the Gd4RhIn-type structure, space group F 4̄3m, Z = 16. The four gadolinium compounds were characterized by single crystal X-ray diffractometer data: a = 1361.7(1) pm, wR2 = 0.062, 456 F2 values, 19 variables for Gd4NiCd; a = 1382.1(2) pm, wR2 = 0.077, 451 F2 values, 19 variables for Gd4PdCd; a = 1363.6(2) pm, wR2 = 0.045, 494 F2 values, 19 variables for Gd4IrCd; a = 1379.0(1) pm, wR2 = 0.045, 448 F2 values, 19 variables for Gd4PtCd. The rare earth atoms build up transition metal-centered trigonal prisms which are condensed via common corners and edges, leading to three-dimensional adamantane-related networks. The cadmium atoms form Cd4 tetrahedra which fill voids left in the prisms’ network.


1993 ◽  
Vol 07 (01n03) ◽  
pp. 391-394 ◽  
Author(s):  
G. CORDIER ◽  
R. HENSELEIT

Structural characteristics of a number of ternary rare earth/transition metal/aluminium compounds are hexagonal nets of the AlB 2-type, Kagomé nets and tetragonal pyramides. Crystal structures of the new compounds in the ternary Yb-T-Al systems contain units and sections of them. Kagomé nets stacked in an ..ABAB.. sequence are observed in YbAg1.5Al0.5 ( MgZn 2-type). The crystal structure of Yb8Ag21Al45 is related to the BaHg 11-type. YbAu0.8Al3.2 ( CaZn 2 Al 2-type) contains tetragonal pyramides which are connected by common edges. Fragments of the AlB 2- and BaAl 4-type structure are present in Yb5Au15Al16. YbPdAl2 and YbPtAl2 ( YbPdAl 2-type) contain pentagonal prisms as the characteristic structural elements.


2010 ◽  
Vol 110 (3) ◽  
pp. 210-217 ◽  
Author(s):  
N. V. Mushnikov ◽  
V. S. Gaviko ◽  
E. G. Gerasimov ◽  
P. B. Terent’ev ◽  
I. A. Tkach

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