Paradoxes and Paradigms: When Do Alkali Metal (Na) and Alkaline Earth (Mg, Ca) Halides (F, Cl) Completely Dissociate? A Combined Analytical and Thermochemical Approach

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A series of novel excess electron compounds M(NH3)6NaCl and M(NH3)6Na2 (M = Mg and Ca) were designed, in which the lowest-energy M(NH3)6Na2 compounds are the first alkalides containing double alkali metal anions.


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