Synthesis of α-Fluorinated Phosphonoacetate Derivatives Using Electrophilic Fluorine Reagents: Perchloryl Fluoride versus 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate) (Selectfluor®).

Mong S. Marma; Leslie A. Khawli; Vahak Harutunian; Boris A. Kashemirov; Charles E. McKenna

doi:10.1002/chin.200614182

Synthesis of α-Fluorinated Phosphonoacetate Derivatives Using Electrophilic Fluorine Reagents: Perchloryl Fluoride versus 1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate) (Selectfluor®).

ChemInform ◽

10.1002/chin.200614182 ◽

2006 ◽

Vol 37 (14) ◽

Author(s):

Mong S. Marma ◽

Leslie A. Khawli ◽

Vahak Harutunian ◽

Boris A. Kashemirov ◽

Charles E. McKenna

Keyword(s):

Perchloryl Fluoride

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Reactions of Perchloryl Fluoride with Organic Compounds. I. Perchlorylation of Aromatic Compounds1

Journal of the American Chemical Society ◽

10.1021/ja01552a069 ◽

1958 ◽

Vol 80 (19) ◽

pp. 5286-5288 ◽

Cited By ~ 16

Author(s):

C. E. Inman ◽

R. E. Oesterling ◽

E. A. Tyczkowski

Keyword(s):

Organic Compounds ◽

Perchloryl Fluoride

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Low temperature heat capacity, dielectric constant, and thermodynamic properties of solid perchloryl fluoride

The Journal of Chemical Physics ◽

10.1063/1.433950 ◽

1977 ◽

Vol 66 (2) ◽

pp. 736-742 ◽

Cited By ~ 6

Author(s):

K. R. Mountfield ◽

R. D. Weir

Keyword(s):

Heat Capacity ◽

Dielectric Constant ◽

Low Temperature ◽

Thermodynamic Properties ◽

Temperature Heat ◽

Low Temperature Heat Capacity ◽

Perchloryl Fluoride

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ChemInform Abstract: ESR SPECTRA AND STRUCTURE OF THE PERCHLORYL FLUORIDE RADICAL ANION (FCLO3-): A 33 VALENCE ELECTRON RADICAL WITH C3V SYMMETRY

Chemischer Informationsdienst ◽

10.1002/chin.198210008 ◽

1982 ◽

Vol 13 (10) ◽

Author(s):

A. HASEGAWA ◽

F. WILLIAMS

Keyword(s):

Radical Anion ◽

Valence Electron ◽

Esr Spectra ◽

Perchloryl Fluoride

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ESR spectra and structure of the perchloryl fluoride radical anion (FClO3-): a 33 valence electron radical with C3v symmetry

Journal of the American Chemical Society ◽

10.1021/ja00414a003 ◽

1981 ◽

Vol 103 (24) ◽

pp. 7051-7054 ◽

Cited By ~ 6

Author(s):

A. Hasegawa ◽

Ffrancon Williams

Keyword(s):

Radical Anion ◽

Valence Electron ◽

Esr Spectra ◽

Perchloryl Fluoride

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ChemInform Abstract: PHOSPHORYLATION OF OLEFINS WITH PHOSPHORUS TRIBROMIDE IN THE PRESENCE OF PERCHLORYL FLUORIDE

Chemischer Informationsdienst ◽

10.1002/chin.197638300 ◽

1976 ◽

Vol 7 (38) ◽

pp. no-no

Author(s):

S. V. FRIDLAND ◽

N. V. DZHITRIEVA ◽

I. V. VIGALOK ◽

R. A. SALAKHUTDINOV

Keyword(s):

Phosphorus Tribromide ◽

Perchloryl Fluoride

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5. Introduction of Fluorine with Perchloryl Fluoride (FCIO3)

Organo-Fluorine Compounds ◽

10.1055/b-0035-111131 ◽

1998 ◽

Keyword(s):

Perchloryl Fluoride

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Elastomers Resistant to Rocket Propellants

Rubber Chemistry and Technology ◽

10.5254/1.3547131 ◽

1966 ◽

Vol 39 (4) ◽

pp. 1222-1232 ◽

Cited By ~ 4

Author(s):

Joseph Green ◽

N. B. Levine ◽

W. Sheehan

Keyword(s):

Silicone Rubber ◽

Butyl Rubber ◽

Nitrogen Tetroxide ◽

Ethylene Propylene ◽

Rocket Propellants ◽

Ethylene Propylene Rubber ◽

Limited Application ◽

Perchloryl Fluoride

Abstract Resistance of polymers to hydrazine-type fuels, Hybaline A-5, nitrogen tetroxide, and fluorine-containing oxidizers was investigated. Elastomers found suitable for application in hydrazine-type fuels and Hybaline A-5 environments are butyl and ethylene propylene rubbers. Carboxy-nitroso rubber is recommended for long term exposure to nitrogen tetroxide at 165° F while resin-cured butyl rubber is satisfactory for limited application. Fluorocarbon plastics and silicone rubber are most suitable for use with oxygen difluoride, and Teflon, polyethylene, and ethylene propylene rubber with a perchloryl fluoride-tetrafluorohydrazine mixture. Chlorine trifluoride is a very reactive oxidizer and Teflon, Kel-F 81, and uncured nitroso rubber gum are suitable only for limited application.

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