Phase Behavior and Microstructure in Aqueous Mixtures of Cationic and Anionic Surfactants

ChemInform ◽  
2006 ◽  
Vol 37 (13) ◽  
Author(s):  
Eric W. Kaler ◽  
Kathi L. Herrington ◽  
Daniel J. Iampietro ◽  
Bret A. Coldren ◽  
Hee-Tae Jung ◽  
...  
Keyword(s):  
Phase Behavior ◽  
Anionic Surfactants ◽  
Aqueous Mixtures ◽  
Cationic And Anionic Surfactants

Phase behavior of cationic and anionic surfactants at low concentrations

1992 ◽  
Vol 50 (1) ◽  
pp. 694-695
Author(s):  
E. Naranjo
Keyword(s):  
Phase Behavior ◽  
Structural Characterization ◽  
Dynamic Systems ◽  
Anionic Surfactants ◽  
Intermolecular Forces ◽  
Stable Form ◽  
Surfactant Mixtures ◽  
Low Concentrations ◽  
Cationic And Anionic Surfactants ◽  
General Method

Equilibrium vesicles, those which are the stable form of aggregation and form spontaneously on mixing surfactant with water, have never been demonstrated in single component bilayers and only rarely in lipid or surfactant mixtures. Designing a simple and general method for producing spontaneous and stable vesicles depends on a better understanding of the thermodynamics of aggregation, the interplay of intermolecular forces in surfactants, and an efficient way of doing structural characterization in dynamic systems.

Spontaneous Vesicles and other Solution Structures in Catanionic Mixtures

1991 ◽  
Vol 248 ◽  
Author(s):  
Eric W. Kaler ◽  
Kathleen L. Herrington ◽  
Joseph A. N. Zasadzinski
Keyword(s):  
Anionic Surfactants ◽  
Structural Studies ◽  
Aqueous Mixtures ◽  
Approach To Equilibrium ◽  
Equilibrium Form ◽  
Solution Structures ◽  
Catanionic Vesicles ◽  
Cationic And Anionic Surfactants ◽  
Physical And Chemical ◽  
Catanionic Mixtures

AbstractWe have prepared spontaneous, single-walled, equilibrium vesicles of controlled size and surface charge from aqueous mixtures of simple, commercially available, single-tailed cationic and anionic surfactants. We believe vesicle formation results from the production of anion-cation surfactant pairs which then act as double-tailed zwitterionic surfactants. Although unilamellar vesicles have been created by numerous physical and chemical techniques from multilamellar dispersions, all such vesicle systems revert to the equilibrium, multilamellar phase over time. These catanionic vesicles are stable for periods as long as several years and appear to be the equilibrium form of aggregation. Here we review the phase behavior and structural studies of several such mixtures, with particular focus on the effect of surfactant tail lengths on size and location of the vesicle phase in the appropriate phase diagram. The approach to equilibrium is also discussed.

scholarly journals Phase Behavior of Aqueous Mixtures of Cationic-anionic Surfactants

1995 ◽  
Vol 11 (09) ◽  
pp. 818-823
Author(s):  
Xiao Jin-Xin ◽  
◽  
Zhao Guo-Xi
Keyword(s):  
Phase Behavior ◽  
Anionic Surfactants ◽  
Aqueous Mixtures

Phase behavior in mixtures of cationic and anionic surfactants in aqueous solutions

1995 ◽  
Vol 273 (2) ◽  
pp. 182-188 ◽  
Author(s):  
N. Filipović-Vinceković ◽  
M. Bujan ◽  
Đ. Dragčević ◽  
N. Nekić
Keyword(s):  
Aqueous Solutions ◽  
Phase Behavior ◽  
Anionic Surfactants ◽  
Cationic And Anionic Surfactants

Adsorption of cationic and anionic surfactants on natural and synthetic carbonate materials

2013 ◽  
Vol 408 ◽  
pp. 164-172 ◽  
Author(s):  
Kun Ma ◽  
Leyu Cui ◽  
Yezi Dong ◽  
Tianlong Wang ◽  
Chang Da ◽  
...  
Keyword(s):  
Anionic Surfactants ◽  
Cationic And Anionic Surfactants ◽  
Carbonate Materials ◽  
Natural And Synthetic

Temperature-Dependent Vesicle Formation of Aqueous Solutions of Mixed Cationic and Anionic Surfactants

Langmuir ◽  
2004 ◽  
Vol 20 (6) ◽  
pp. 2117-2122 ◽  
Author(s):  
Koji Tsuchiya ◽  
Hisanori Nakanishi ◽  
Hideki Sakai ◽  
Masahiko Abe
Keyword(s):  
Aqueous Solutions ◽  
Anionic Surfactants ◽  
Vesicle Formation ◽  
Temperature Dependent ◽  
Cationic And Anionic Surfactants
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