scholarly journals Suzuki Coupling of Aryl Chlorides with Phenylboronic Acid in Water, Using Microwave Heating with Simultaneous Cooling.

ChemInform ◽  
2005 ◽  
Vol 36 (42) ◽  
Author(s):  
Riina K. Arvela ◽  
Nicholas E. Leadbeater
Keyword(s):  
Microwave Heating ◽  
Phenylboronic Acid ◽  
Suzuki Coupling ◽  
Aryl Chlorides

Synthesis, characterization, and application of palladium complexes containing bis(aminophosphine) ligands

2017 ◽  
Vol 95 (10) ◽  
pp. 1041-1044 ◽  
Author(s):  
Christina Jones ◽  
Matthew Timm ◽  
Jason D. Masuda ◽  
Aibing Xia
Keyword(s):  
Single Crystal ◽  
Phenylboronic Acid ◽  
Suzuki Coupling ◽  
Palladium Complexes ◽  
Coupling Reactions ◽  
Single Crystal Diffraction ◽  
X Ray ◽  
Aryl Chlorides

Two palladium complexes containing bis(aminophosphine) ligands have been prepared and characterized. Their solid structures were determined by X-ray single crystal diffraction studies. They were successfully employed in the Suzuki coupling reactions of phenylboronic acid and various aryl chlorides.

The Suzuki Coupling of Aryl Chlorides under Microwave Heating

2004 ◽  
Vol 346 (13-15) ◽  
pp. 1627-1630 ◽  
Author(s):  
Robin B. Bedford ◽  
Craig P. Butts ◽  
Timothy E. Hurst ◽  
Pelle Lidström
Keyword(s):  
Microwave Heating ◽  
Suzuki Coupling ◽  
Aryl Chlorides

Chiral Mn(III) Salen Complex Immobilized on CuFe2O4@SiO2-NH2 NPs: A Cheap and Efficient Catalyst for N-arylation of Aryl Halides and Phenylboronic Acid Under Mild Conditions

2020 ◽  
Vol 17 (11) ◽  
pp. 857-863
Author(s):  
Mohammad Ali Nasseri ◽  
Seyyedeh Ameneh Alavi ◽  
Milad Kazemnejadi ◽  
Ali Allahresani
Keyword(s):  
Phenylboronic Acid ◽  
Significant Loss ◽  
Aryl Halides ◽  
Coupling Reactions ◽  
Efficient Catalyst ◽  
Aryl Chlorides ◽  
Mild Conditions ◽  
Cross Coupling Reactions ◽  
Salen Complex ◽  
Ft Ir

A convenient and efficient chiral CuFe2O4@SiO2-Mn(III) Ch.salen nanocatalyst has been developed for the C-N cross-coupling reactions of aryl halides/ phenylboronic acid with N-heterocyclic compounds in water and/or DMSO under mild conditions. The catalyst could be applied for the N-arylation of a variety of nitrogen-containing heterocycles with aryl chlorides, bromides, iodides and phenylboronic acid under mild conditions. Moderate to good yields were achieved for all substrates. The structure of catalyst was characterized using various techniques including FT-IR, FE-SEM, EDX, XRD, TEM and TGA. The catalyst can be simply recovered and reused for several times without significant loss of activity.

The Synthesis and Catalytic Application of a New Class of Imprinted Silica

2003 ◽  
Vol 787 ◽  
Author(s):  
John D. Bass ◽  
Sandra L. Anderson ◽  
Alexander Katz
Keyword(s):  
Rational Design ◽  
Chemical Reactivity ◽  
Phenylboronic Acid ◽  
Coupling Reaction ◽  
Suzuki Coupling ◽  
Outer Sphere ◽  
Suzuki Coupling Reaction ◽  
New Class ◽  
Catalytic Application ◽  
Rate Acceleration

AbstractThe effect of chemical environment surrounding a synthetic heterogeneous catalyst active site is investigated using the hydrophilic imprinting of silica. Two model reaction systems have been used for this study: (i) Knoevenagel condensation of 3-nitrobenzaldehyde and malononitrile and (ii) Suzuki coupling of bromobenzene and phenylboronic acid. Using a catalyst in which isolated imprinted amines are surrounded by an acidic silanol-rich environment led to rate accelerations of over 120-fold relative to catalysts in which the amines are surrounded by a hydrophobic environment consisting of trimethylsilyl functional groups for system (i). This result parallels our previous study on the effect of the outer sphere composition on rate acceleration of Knoevenagel reactions using isophthalaldehyde as the aldehyde reactant. We also extended our method for the hydrophilic imprinting of bulk silica to organometallic systems, by successfully synthesizing a tethered palladium complex within the imprinted pocket. This material was used as an active catalyst for (ii). Our results show that a hydrophobic framework environment results in higher initial turnover frequencies than an acidic silanol-rich framework for the Suzuki coupling reaction of bromobenzene and phenylboronic acid, albeit with a lower overall effect than observed in the Knoevenagel system (i). Altogether, these results demonstrate the control of chemical reactivity via the rational design of the outer sphere using an imprinting approach.

Di- and tri-alkylphosphine adducts of S-donor palladacycles as catalysts in the Suzuki coupling of aryl chlorides

2004 ◽  
pp. 3864 ◽  
Author(s):  
Robin B. Bedford ◽  
Catherine S. J. Cazin ◽  
Michael B. Hursthouse ◽  
Mark E. Light ◽  
V�ronique J. M. Scordia
Keyword(s):  
Suzuki Coupling ◽  
Aryl Chlorides

ChemInform Abstract: New Cyclopalladated Benzothiophenes: A Catalyst Precursor for the Suzuki Coupling of Deactivated Aryl Chlorides.

ChemInform ◽  
2010 ◽  
Vol 41 (49) ◽  
pp. no-no
Author(s):  
Madavu Salian Subhas ◽  
Shailesh S. Racharlawar ◽  
B. Sridhar ◽  
P. Kavin Kennady ◽  
Pravin R. Likhar ◽  
...  
Keyword(s):  
Suzuki Coupling ◽  
Catalyst Precursor ◽  
Aryl Chlorides

scholarly journals Ultra-small palladium nano-particles synthesized using bulky S/Se and N donor ligands as a stabilizer: application as catalysts for Suzuki–Miyaura coupling

RSC Advances ◽  
2019 ◽  
Vol 9 (39) ◽  
pp. 22313-22319 ◽  
Author(s):  
Preeti Oswal ◽  
Aayushi Arora ◽  
Jolly Kaushal ◽  
Gyandshwar Kumar Rao ◽  
Sushil Kumar ◽  
...  
Keyword(s):  
Suzuki Coupling ◽  
Pd Nanoparticles ◽  
Nano Particles ◽  
Secondary Amines ◽  
Donor Ligands ◽  
Catalyst Loading ◽  
Aryl Chlorides ◽  
Low Catalyst Loading

Monodispersed ultrasmall Pd nanoparticles synthesized utilizing bulky organochalcogen secondary amines as stabilizers and application in Suzuki coupling of aryl chlorides at low catalyst loading.

scholarly journals A tetranuclear CuII2DyIII2 coordination cluster as a Suzuki (C–C) coupling reaction promoter

2018 ◽  
Vol 47 (48) ◽  
pp. 17202-17205 ◽  
Author(s):  
Prashant Kumar ◽  
Kieran Griffiths ◽  
Christopher E. Anson ◽  
Annie K. Powell ◽  
George E. Kostakis
Keyword(s):  
Phenylboronic Acid ◽  
Coupling Reaction ◽  
Suzuki Coupling ◽  
Aryl Halides ◽  
Environmentally Benign ◽  
Suzuki Coupling Reaction

The air stable and high yielding tetranuclear coordination cluster [CuII2DyIII2L4(NO3)2(CH3CN)2]·2(CH3CN) promotes the Suzuki coupling reaction of phenylboronic acid with substituted aryl halides under environmentally benign conditions.

Sign in / Sign up

Export Citation Format

Share Document