A One-Pot Synthesis of 3,4-Dihydropyrimidin-2-(1H)-ones from Primary Alcohols Promoted by Bi(NO3)3×5H2O in Two Different Media: Organic Solvent and Ionic Liquid.

ChemInform ◽  
2005 ◽  
Vol 36 (37) ◽  
Author(s):  
Ahmad R. Khosropour ◽  
Mohammd M. Khodaei ◽  
Mojtaba Beygzadeh ◽  
Mahbubeh Jokar
Keyword(s):  
Ionic Liquid ◽  
Organic Solvent ◽  
Primary Alcohols ◽  
One Pot ◽  
One Pot Synthesis

A One-Pot Synthesis of 3,4-Dihydropyrimidin-2-(1H)-ones from Primary Alcohols Promoted by Bi(NO3)3·5H2O in Two Different Media: Organic Solvent and Ionic Liquid

Heterocycles ◽  
2005 ◽  
Vol 65 (4) ◽  
pp. 767 ◽  
Author(s):  
Ahmad Reza Khosropour ◽  
Ahmad R. Khosropour ◽  
Mohammd M. Khodaei ◽  
Mojtaba Beygzadeh ◽  
Mahbubeh Jokar
Keyword(s):  
Ionic Liquid ◽  
Organic Solvent ◽  
Primary Alcohols ◽  
One Pot ◽  
One Pot Synthesis

A one-pot synthesis of benzimidazoles via aerobic oxidative condensation of benzyl alcohols with o-phenylenediamines catalyzed by [MIMPs]+Cl-/NaNO2/TEMPO

2020 ◽  
Vol 44 (9-10) ◽  
pp. 557-565
Author(s):  
Zhenzhen Geng ◽  
Hong-yu Zhang ◽  
Guohui Yin ◽  
Yuecheng Zhang ◽  
Jiquan Zhao
Keyword(s):  
Ionic Liquid ◽  
Catalytic System ◽  
Sodium Nitrite ◽  
High Efficiency ◽  
Oxidative Condensation ◽  
Imidazolium Chloride ◽  
One Pot ◽  
Benzyl Alcohols ◽  
One Pot Synthesis ◽  
The One

The ionic liquid 1-methyl-3-(3-sulfopropyl)imidazolium chloride ([MIMPs]+Cl-) in combination with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and sodium nitrite (NaNO2) as a catalytic system demonstrates high efficiency in the one-pot two-step aerobic oxidative condensation of benzyl alcohols with 1,2-phenylenediamines to give benzimidazoles. Various benzimidazoles are obtained in good to excellent yields by this strategy.

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