Green Chemistry — Suzuki Cross Coupling in Aqueous Media

ChemInform ◽  
2005 ◽  
Vol 36 (35) ◽  
Author(s):  
Robert Franzen ◽  
Youjun Xu
Keyword(s):  
Green Chemistry ◽  
Aqueous Media ◽  
Cross Coupling

Review on green chemistry — Suzuki cross coupling in aqueous media

2005 ◽  
Vol 83 (3) ◽  
pp. 266-272 ◽  
Author(s):  
Robert Franzén ◽  
Youjun Xu
Keyword(s):  
Green Chemistry ◽  
Aqueous Media ◽  
Suzuki Reaction ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Aqueous Synthesis ◽  
Cross Coupling Reactions ◽  
Cross Coupling Reaction ◽  
Metal Catalyzed

The Suzuki cross-coupling reaction is a very efficient, reliable, and environmentally friendly method for the introduction of novel carbon–carbon bonds into molecules. This review summarizes recent advances in the use of the reaction in aqueous media with a focus on different types of ligands and the ligandless protocols currently in use. Several synthetic targets for the reaction have been mentioned. The work summarizes recent results from studies on asymmetric Suzuki reactions performed in organic – aqueous mixed solvents.Key words: Suzuki reaction, green chemistry, metal-catalyzed cross-coupling reactions, aqueous synthesis media.

Transition-Metal-Free Synthetic Strategies for the Cross-Coupling Reactions in Water: A Green Approach

2020 ◽  
Vol 07 ◽  
Author(s):  
Tanmay Chatterjee ◽  
Nilanjana Mukherjee
Keyword(s):  
Transition Metal ◽  
Organic Solvents ◽  
Aqueous Media ◽  
Cross Coupling ◽  
Transition Metal Catalysts ◽  
Synthetic Methods ◽  
Coupling Reactions ◽  
Organic Transformations ◽  
Green Approach ◽  
Dehydrogenative Coupling

Abstract: A natural driving force is always working behind the synthetic organic chemists towards the development of ‘green’ synthetic methodologies for the synthesis of useful classes of organic molecules having potential applications. The majority of the essential classes of organic transformations, including C-C and C-X (X = heteroatom) bond-forming crosscoupling reactions, cross dehydrogenative-coupling (CDC) mostly rely on the requirement of transition-metal catalysts and hazardous organic solvents. Hence, the scope in developing green synthetic strategies by avoiding the use of transitionmetal catalysts and hazardous organic solvents for those important and useful classes of organic transformations is very high. Hence, several attempts are made so far. Water being the most abundant, cheap, and green solvent in the world; numerous synthetic methods have been developed in an aqueous medium. In this review, the development of transitionmetal- free green synthetic strategies for various important classes of organic transformations such as C-C and C-X bondforming cross-coupling, cross dehydrogenative-coupling, and oxidative-coupling in an aqueous media is discussed.

NiFe2O4@SiO2@ZrO2/SO42−/Cu/Co nanoparticles: a novel, efficient, magnetically recyclable and bimetallic catalyst for Pd-free Suzuki, Heck and C–N cross-coupling reactions in aqueous media

2021 ◽  
Author(s):  
Seyyedeh Ameneh Alavi G. ◽  
Mohammad Ali Nasseri ◽  
Milad Kazemnejadi ◽  
Ali Allahresani ◽  
Mahdi HussainZadeh
Keyword(s):  
Bimetallic Nanoparticles ◽  
Bimetallic Catalyst ◽  
Aqueous Media ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
The Novel ◽  
Cross Coupling Reactions ◽  
Co Nanoparticles

The novel heterogeneous bimetallic nanoparticles of Cu–Co were synthesized and successfully applied as a recyclable magnetically catalyst in Heck, Suzuki, and C–N cross-coupling via a quick, easy, efficacious and environmentally protocol.

scholarly journals Alum Catalyzed Simple, Efficient, and Green Synthesis of 2-[3-Amino-5-methyl-5-(pyridin-3-yl)-1,5-dihydro-4H-1,2,4-triazol-4-yl]propanoic Acid Derivatives in Aqueous Media

2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Harshita Sachdeva ◽  
Diksha Dwivedi ◽  
Rekha Saroj
Keyword(s):  
Amino Acids ◽  
Green Chemistry ◽  
Green Synthesis ◽  
Aqueous Media ◽  
Propanoic Acid ◽  
Ft Ir ◽  
C Nmr

Alum (KAl(SO4)2·12H2O) is an inexpensive, efficient, and nontoxic catalyst used for the synthesis of 2-[3-amino-5-methyl-5-(pyridin-3-yl)-1,5-dihydro-4H-1,2,4-triazol-4-yl]propanoic acid derivatives in aqueous media by the reaction of 3-acetyl pyridine(1), amino acids(2)/(6), and thiosemicarbazide(4)at 80°C. This methodology offers significant improvements for the synthesis of products with regards to the yield of products, simplicity in operation, and green aspects by avoiding toxic catalysts which uphold the motto of green chemistry. Synthesized compounds have been characterized by FT-IR,13C NMR, and1HNMR spectroscopy.

scholarly journals Recyclable glucose-derived palladium(0) nanoparticles as in situ-formed catalysts for cross-coupling reactions in aqueous media

RSC Advances ◽  
2016 ◽  
Vol 6 (20) ◽  
pp. 16115-16121 ◽  
Author(s):  
Jason E. Camp ◽  
Jay J. Dunsford ◽  
Oliver S. G. Dacosta ◽  
Rebecca K. Blundell ◽  
James Adams ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Aqueous Media ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

Renewable sugar-derived palladium(0) nanoparticles (PdNPs) are effective as in situ formed catalysts for cross-coupling reactions in aqueous solutions.

ChemInform Abstract: In/InCl3-Mediated Cross-Coupling Reactions of Methyl Vinyl Ketone with Benzaldehyde in Aqueous Media.

ChemInform ◽  
2001 ◽  
Vol 32 (14) ◽  
pp. no-no
Author(s):  
Soyeon Kang ◽  
Taeg-Su Jang ◽  
Gyochang Keum ◽  
Soon Bang Kang ◽  
So-Yeop Han ◽  
...  
Keyword(s):  
Aqueous Media ◽  
Cross Coupling ◽  
Vinyl Ketone ◽  
Methyl Vinyl Ketone ◽  
Coupling Reactions ◽  
Methyl Vinyl ◽  
Cross Coupling Reactions
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