Metallacyclopentadienes: Structural Features and Coordination in Transition Metal Complexes

ChemInform ◽  
2004 ◽  
Vol 35 (49) ◽  
Author(s):  
F. M. Dolgushin ◽  
A. I. Yanovsky ◽  
M. Yu. Antipin
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Structural Features

scholarly journals Half- and mixed-sandwich metallacarboranes for potential applications in medicine

2019 ◽  
Vol 91 (4) ◽  
pp. 563-573 ◽  
Author(s):  
Marta Gozzi ◽  
Benedikt Schwarze ◽  
Evamarie Hey-Hawkins
Keyword(s):  
Organic Chemistry ◽  
Transition Metal ◽  
Transition Metals ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Structural Features ◽  
Biological Stability ◽  
Potential Applications ◽  
Sandwich Type ◽  
Isolobal Analogy

Abstract Today, medicinal chemistry is still clearly dominated by organic chemistry, and commercially available boron-based drugs are rare. In contrast to hydrocarbons, boranes prefer the formation of polyhedral clusters via delocalized 3c2e bonds, such as polyhedral dicarba-closo-dodecaborane(12) (closo-C2B10H12). These clusters have remarkable biological stability, and the three isomers, 1,2- (ortho), 1,7- (meta), and 1,12-dicarba-closo-dodecaborane(12) (para), have attracted much interest due to their unique structural features. Furthermore, anionic nido clusters ([7,8-C2B9H11]2−), derived from the neutral icosahedral closo cluster 1,2-dicarba-closo-dodecaborane(12) by deboronation followed by deprotonation are suitable ligands for transition metals and offer the possibility to form metallacarboranes, for example via coordination through the upper pentagonal face of the cluster. The isolobal analogy between the cyclopentadienyl(–1) ligand (Cp−) and [C2B9H11]2− clusters (dicarbollide anion, Cb2−) is the motivation in using Cb2− as ligand for coordination to a metal center to design compounds for various applications. This review focuses on potential applications of half- and mixed-sandwich-type transition metal complexes in medicine.

Transition-metal complexes of superstructured cyclidene macrobicycles: structural features and their chemical consequences. 3. Cyclidenes with long polymethylene bridges

1990 ◽  
Vol 29 (14) ◽  
pp. 2599-2607 ◽  
Author(s):  
Nathaniel W. Alcock ◽  
Peter A. Padolik ◽  
Graham A. Pike ◽  
Masaaki Kojima ◽  
Colin J. Cairns ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Structural Features

Metallacyclopentadienes: structural features and coordination in transition metal complexes

2004 ◽  
Vol 73 (6) ◽  
pp. 517-540 ◽  
Author(s):  
Fedor M Dolgushin ◽  
Aleksandr I Yanovsky ◽  
Mikhail Yu Antipin
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Structural Features

scholarly journals Synthesis and Structure of Aryl Phosphorus Compounds

2020 ◽  
Vol 12 (4) ◽  
pp. 5-50
Author(s):  
A. Zykova ◽  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Organophosphorus Compounds ◽  
Structural Features ◽  
Phosphorus Compounds ◽  
Chemical Transformations ◽  
State University ◽  
Late 20Th Century ◽  
Classical Studies

Based on an analysis of the literature published from the late 20th century to the beginning of the 21st century, methods for the synthesis of some complex tetraorganylphosphonium salts are systematized and described, along with the features of the chemical transformations of pentaphenylphosphorus, which was first obtained in 1953. The tetraorganylphosphonium salts were known much earlier, however, the features of the synthesis of transition metal complexes, which are usually obtained from tetraorganylphosphorus halides and metal halides, have not been sufficiently studied. The present review is devoted to the discussion of these topics, since the famous Wittig Reaction is associated with aryl phosphorus compounds, which allows synthesizing alkenes of a given structure, and derivatives of transition metals rightfully occupy a special place among catalysts of various chemical processes. The continuation of these classical studies in the field of chemistry of organoelemental compounds takes place at one of the leading universities in Russia - South Ural State University in the laboratory of chemistry of organoelemental compounds at the Faculty of Chemistry. This article aims at familiarizing the reader with the achievements of Professor V.V. Sharutin and his students in the field of organophosphorus compounds. The main attention is paid to the reactions of pentaphenylphosphorus and its derivatives, as well as methods for the synthesis of ionic complexes of silver, gold, copper, titanium, zirconium, hafnium, ruthenium, osmium, cobalt, rhodium, iridium, palladium and platinum with tetraorganylphosphonium cations. The structural features of the described compounds and the possibility of using transition metal complexes in some catalytic reactions are described.

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

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