scholarly journals Palladium-Catalyzed Regioselective Hydrodebromination of Dibromoindoles: Application to the Enantioselective Synthesis of Indolodioxane U86192A.

ChemInform ◽  
2004 ◽  
Vol 35 (37) ◽  
Author(s):  
Junghyun Chae ◽  
Stephen L. Buchwald
Keyword(s):  
Enantioselective Synthesis ◽  
Palladium Catalyzed

Novel Chiral Ligands for Palladium-catalyzed Asymmetric Allylic Alkylation/ Asymmetric Tsuji-Trost Reaction: A Review

2019 ◽  
Vol 23 (11) ◽  
pp. 1168-1213 ◽  
Author(s):  
Samar Noreen ◽  
Ameer Fawad Zahoor ◽  
Sajjad Ahmad ◽  
Irum Shahzadi ◽  
Ali Irfan ◽  
...  
Keyword(s):  
Asymmetric Catalysis ◽  
Enantioselective Synthesis ◽  
Chiral Ligands ◽  
Allylic Alkylation ◽  
Research Groups ◽  
Asymmetric Allylic Alkylation ◽  
Catalytic Potential ◽  
Long Time ◽  
Palladium Catalyzed ◽  
Alkylation Reactions

Background: Asymmetric catalysis holds a prestigious role in organic syntheses since a long time and chiral inductors such as ligands have been used to achieve the utmost desired results at this pitch. The asymmetric version of Tsuji-Trost allylation has played a crucial role in enantioselective synthesis. Various chiral ligands have been known for Pdcatalyzed Asymmetric Allylic Alkylation (AAA) reactions and exhibited excellent catalytic potential. The use of chiral ligands as asymmetric inductors has widened the scope of Tsuji-Trost allylic alkylation reactions. Conclusion: Therefore, in this review article, a variety of chiral inductors or ligands have been focused for palladium catalyzed asymmetric allylic alkylation (Tsuji-Trost allylation) and in this regard, recently reported literature (2013-2017) has been described. The use of ligands causes the induction of enantiodiscrimination to the allylated products, therefore, the syntheses of various kinds of ligands have been targeted by many research groups to employ in Pd-catalyzed AAA reactions.

Palladium-Catalyzed Enantioselective Synthesis of Cyclic Sulfamidates and Application to a Synthesis of Verubecestat

2018 ◽  
Vol 20 (5) ◽  
pp. 1265-1268 ◽  
Author(s):  
Wenyong Chen ◽  
Dongfang Meng ◽  
Blaise N’Zemba ◽  
William J. Morris
Keyword(s):  
Enantioselective Synthesis ◽  
Palladium Catalyzed

scholarly journals Enantioselective Synthesis of P-Stereogenic Benzophospholanes via Palladium-Catalyzed Intramolecular Cyclization.

ChemInform ◽  
2007 ◽  
Vol 38 (30) ◽  
Author(s):  
Tim J. Brunker ◽  
Brian J. Anderson ◽  
Natalia F. Blank ◽  
David S. Glueck ◽  
Arnold L. Rheingold
Keyword(s):  
Intramolecular Cyclization ◽  
Enantioselective Synthesis ◽  
Palladium Catalyzed

scholarly journals Palladium-Catalyzed Regio- and Enantioselective Synthesis of Allylic Amines Featuring Tetrasubstituted Tertiary Carbons

2016 ◽  
Vol 138 (43) ◽  
pp. 14194-14197 ◽  
Author(s):  
Aijie Cai ◽  
Wusheng Guo ◽  
Luis Martínez-Rodríguez ◽  
Arjan W. Kleij
Keyword(s):  
Enantioselective Synthesis ◽  
Allylic Amines ◽  
Palladium Catalyzed

Desymmetrization‐Oriented Enantioselective Synthesis of Silicon‐Stereogenic Silanes by Palladium‐Catalyzed C−H Olefinations

2019 ◽  
Vol 14 (12) ◽  
pp. 2082-2085 ◽  
Author(s):  
Yan Lin ◽  
Wei‐Yang Ma ◽  
Zheng Xu ◽  
Zhan‐Jiang Zheng ◽  
Jian Cao ◽  
...  
Keyword(s):  
Enantioselective Synthesis ◽  
Palladium Catalyzed
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