Multistep Microwave-Assisted Solvent-Free Organic Reactions: Synthesis of 4-Oxo-tetrahydro-pyridine.

ChemInform ◽  
2004 ◽  
Vol 35 (24) ◽  
Author(s):  
Mauro Panunzio ◽  
Maria Antonietta Lentini ◽  
Eileen Campana ◽  
Giorgio Martelli ◽  
Emiliano Tamanini ◽  
...  
Keyword(s):  
Solvent Free ◽  
Organic Reactions ◽  
Microwave Assisted

ChemInform Abstract: Solvent-Free Microwave-Assisted Organic Reactions. Preparation of β-Keto Esters.

ChemInform ◽  
2010 ◽  
Vol 31 (34) ◽  
pp. no-no
Author(s):  
Massimo Gianotti ◽  
Giorgio Martelli ◽  
Giuseppe Spunta ◽  
Eileen Campana ◽  
Mauro Panunzio ◽  
...  
Keyword(s):  
Solvent Free ◽  
Organic Reactions ◽  
Keto Esters ◽  
Microwave Assisted

Multistep Microwave-Assisted Solvent-Free Organic Reactions: Synthesis of 4-Oxo-tetrahydro-pyridine

2004 ◽  
Vol 34 (2) ◽  
pp. 345-359 ◽  
Author(s):  
Mauro Panunzio ◽  
Maria Antonietta Lentini ◽  
Eileen Campana ◽  
Giorgio Martelli ◽  
Emiliano Tamanini ◽  
...  
Keyword(s):  
Solvent Free ◽  
Organic Reactions ◽  
Microwave Assisted

Energy efficiency of heterogeneous catalytic microwave-assisted organic reactions

2014 ◽  
Vol 16 (7) ◽  
pp. 3623-3634 ◽  
Author(s):  
Hyejin Cho ◽  
Fanni Török ◽  
Béla Török
Keyword(s):  
Energy Efficiency ◽  
Solvent Free ◽  
Catalytic Reactions ◽  
Organic Reactions ◽  
Heterogeneous Catalytic ◽  
Microwave Assisted

The energy efficiency of microwave-assisted and conventionally heated solvent-free heterogeneous catalytic reactions was studied.

Microwave-assisted solvent-free organic reactions: Synthesis of β-lactams from 1,3-azadienes

1998 ◽  
Vol 39 (34) ◽  
pp. 6257-6260 ◽  
Author(s):  
Giorgio Martelli ◽  
Giuseppe Spunta ◽  
Mauro Panunzio
Keyword(s):  
Solvent Free ◽  
Organic Reactions ◽  
Microwave Assisted

Solvent-Free Microwave-Assisted Organic Reactions Preparation of β-Keto Esters

2000 ◽  
Vol 30 (10) ◽  
pp. 1725-1730 ◽  
Author(s):  
Massimo Gianotti ◽  
Giorgio Martelli ◽  
Giuseppe Spunta ◽  
Eileen Campana ◽  
Mauro Panunzio ◽  
...  
Keyword(s):  
Solvent Free ◽  
Organic Reactions ◽  
Keto Esters ◽  
Microwave Assisted

scholarly journals Pyrene Carboxylate Ligand Based Coordination Polymers for Microwave-Assisted Solvent-Free Cyanosilylation of Aldehydes

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1101
Author(s):  
Anirban Karmakar ◽  
Anup Paul ◽  
Elia Pantanetti Sabatini ◽  
M. Fátima C. Guedes da Silva ◽  
Armando J. L. Pombeiro
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Metal Ion ◽  
Solvent Free ◽  
Lewis Acidity ◽  
Carboxylate Ligand ◽  
X Ray Diffraction ◽  
X Ray ◽  
Microwave Assisted

The new coordination polymers (CPs) [Zn(μ-1κO1:1κO2-L)(H2O)2]n·n(H2O) (1) and [Cd(μ4-1κO1O2:2κN:3,4κO3-L)(H2O)]n·n(H2O) (2) are reported, being prepared by the solvothermal reactions of 5-{(pyren-4-ylmethyl)amino}isophthalic acid (H2L) with Zn(NO3)2.6H2O or Cd(NO3)2.4H2O, respectively. They were synthesized in a basic ethanolic medium or a DMF:H2O mixture, respectively. These compounds were characterized by single-crystal X-ray diffraction, FTIR spectroscopy, thermogravimetric and elemental analysis. The single-crystal X-ray diffraction analysis revealed that compound 1 is a one dimensional linear coordination polymer, whereas 2 presents a two dimensional network. In both compounds, the coordinating ligand (L2−) is twisted due to the rotation of the pyrene ring around the CH2-NH bond. In compound 1, the Zn(II) metal ion has a tetrahedral geometry, whereas, in 2, the dinuclear [Cd2(COO)2] moiety acts as a secondary building unit and the Cd(II) ion possesses a distorted octahedral geometry. Recently, several CPs have been explored for the cyanosilylation reaction under conventional conditions, but microwave-assisted cyanosilylation of aldehydes catalyzed by CPs has not yet been well studied. Thus, we have tested the solvent-free microwave-assisted cyanosilylation reactions of different aldehydes, with trimethylsilyl cyanide, using our synthesized compounds, which behave as highly active heterogeneous catalysts. The coordination polymer 1 is more effective than 2, conceivably due to the higher Lewis acidity of the Zn(II) than the Cd(II) center and to a higher accessibility of the metal centers in the former framework. We have also checked the heterogeneity and recyclability of these coordination polymers, showing that they remain active at least after four recyclings.

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