Diels—Alder Reactions in Ionic Media : Rate Enhancement with Green Chemistry.

ChemInform ◽  
2004 ◽  
Vol 35 (20) ◽  
Author(s):  
Anil Kumar ◽  
Suvarna S. Deshpande ◽  
Sanjay S. Pawar
Keyword(s):  
Green Chemistry ◽  
Diels Alder ◽  
Rate Enhancement ◽  
Ionic Media

scholarly journals Furoic Acid and Derivatives as Atypical Dienes in Diels-Alder Reactions

2021 ◽  
Author(s):  
Razvan Cioc ◽  
Tom Smak ◽  
Marc Crockatt ◽  
Jan Kees Van der Waal ◽  
Pieter C A Bruijnincx
Keyword(s):  
Green Chemistry ◽  
Cycloaddition Reaction ◽  
Building Blocks ◽  
Diels Alder ◽  
Furoic Acid

The furan Diels-Alder (DA) cycloaddition reaction has become an important tool in green chemistry, being central to the sustainable synthesis of many chemical building blocks. The restriction to electron-rich furans...

scholarly journals Rate Enhancement of Diels—Alder Reactions in Aqueous Perfluorinated Emulsions.

ChemInform ◽  
2007 ◽  
Vol 38 (14) ◽  
Author(s):  
Kohsuke Nishimoto ◽  
Shokaku Kim ◽  
Yoshikazu Kitano ◽  
Masahiro Tada ◽  
Kazuhiro Chiba
Keyword(s):  
Diels Alder ◽  
Rate Enhancement

scholarly journals Origin of rate enhancement and asynchronicity in iminium catalyzed Diels–Alder reactions

2020 ◽  
Vol 11 (31) ◽  
pp. 8105-8112 ◽  
Author(s):  
Pascal Vermeeren ◽  
Trevor A. Hamlin ◽  
Israel Fernández ◽  
F. Matthias Bickelhaupt
Keyword(s):  
Quantum Chemical ◽  
Chemical Activation ◽  
Diels Alder ◽  
Rate Enhancement ◽  
Pauli Repulsion

Quantum chemical activation strain analyses revealed that iminium catalysts accelerate Diels–Alder reactions by reducing the Pauli repulsion between reactants.

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