Yttrium Polyoxometalates. Synthesis and Characterization of a Carbonate-Encapsulated Sandwich-Type Complex.

ChemInform ◽  
2004 ◽  
Vol 35 (10) ◽  
Author(s):  
Xikui Fang ◽  
Travis M. Anderson ◽  
Wade A. Neiwert ◽  
Craig L. Hill
Keyword(s):  
Synthesis And Characterization ◽  
Type Complex ◽  
Sandwich Type

Yttrium Polyoxometalates. Synthesis and Characterization of a Carbonate-Encapsulated Sandwich-Type Complex

2003 ◽  
Vol 42 (26) ◽  
pp. 8600-8602 ◽  
Author(s):  
Xikui Fang ◽  
Travis M. Anderson ◽  
Wade A. Neiwert ◽  
Craig L. Hill
Keyword(s):  
Synthesis And Characterization ◽  
Type Complex ◽  
Sandwich Type

Preparation and Characterization of a Novel Gadolinium Triple-Decker Sandwich-Type Complex with Tetrabenzoporphyrin Ligand

2013 ◽  
Vol 690-693 ◽  
pp. 573-576
Author(s):  
Qi Feng Liu
Keyword(s):  
Room Temperature ◽  
Spectroscopic Properties ◽  
Magnetic Interactions ◽  
Antiferromagnetic Coupling ◽  
Magnetic Studies ◽  
Conjugated Systems ◽  
Type Complex ◽  
Vis Spectroscopy ◽  
Sandwich Type

A novel gadolinium triple-decker sandwich-type complex containing tetrabenzoporphyrin (TBP) ligands-Gd (TBP)3was prepared from porphyrin 1 and Gd (acac)3.nH2O in boiling 1, 2, 4-Tcb for 45~48 h under Ar. Its structure is characterized by Uv-Vis spectroscopy and HR-MS. The spectroscopic properties show that its longest-wavelength visible band (600-800 nm) is obviously red-shifted due to the extension of the π conjugated systems derived from the linear benzoannulation in the TBP ring. The magnetic studies also indicate that there is no magnetic interactions between two Gd (III) ions in the triple-deckers in the range from room temperature down to 20K and very weak antiferromagnetic coupling exists between two Gd (III) ions below 20K.

Silylene-assisted hydride transfer to CO2 and CS2 at a [P2Si]Ru pincer-type complex

2017 ◽  
Vol 46 (43) ◽  
pp. 14757-14761 ◽  
Author(s):  
Matthew T. Whited ◽  
Jia Zhang ◽  
Senjie Ma ◽  
Binh D. Nguyen ◽  
Daron E. Janzen
Keyword(s):  
Hydride Transfer ◽  
Synthesis And Characterization ◽  
Type Complex ◽  
Ru Complexes

The synthesis and characterization of base-stabilized and base-free pincer-type bis(phosphine)/silylene [P2Si]Ru complexes are reported. The base-free complex performs cooperative, silylene-assisted hydride transfer to CO2 and CS2.

Synthesis and Characterization of New Rare‐Earth Sandwich‐Type Tungstoarsenates

2006 ◽  
Vol 36 (4) ◽  
pp. 335-344 ◽  
Author(s):  
Adrian‐Raul Tomşa ◽  
Aglaia Koutsodimou ◽  
Polycarpos Falaras ◽  
Marie‐Claude Bernard ◽  
Vladimir Graban ◽  
...  
Keyword(s):  
Rare Earth ◽  
Synthesis And Characterization ◽  
Sandwich Type
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