A New Method for the Synthesis of Bishydroperoxides Based on a Reaction of Ketals with Hydrogen Peroxide Catalyzed by Boron Trifluoride Complexes.

ChemInform ◽  
2004 ◽  
Vol 35 (1) ◽  
Author(s):  
Alexander O. Terent'ev ◽  
Alexander V. Kutkin ◽  
Maxim M. Platonov ◽  
Yuri N. Ogibin ◽  
Gennady I. Nikishin
2003 ◽  
Vol 44 (39) ◽  
pp. 7359-7363 ◽  
Author(s):  
Alexander O. Terent'ev ◽  
Alexander V. Kutkin ◽  
Maxim M. Platonov ◽  
Yuri N. Ogibin ◽  
Gennady I. Nikishin

2021 ◽  
Vol 299 (10) ◽  
pp. 1567-1575
Author(s):  
Zahra Moradpour ◽  
Mehrdad Helmi Kohnehshahri ◽  
Masoomeh Vahabi Shekarloo ◽  
Vahid Jalili ◽  
Rezvan Zendehdel

RSC Advances ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 2258-2267 ◽  
Author(s):  
Yunfan Qiao ◽  
Rushi Zhao ◽  
Min Zhang ◽  
Hongyang Zhang ◽  
Yuerong Wang ◽  
...  

In this paper, we presented a new method for constructing near-infrared fluorescence probes and their applications in detecting glucose and hydrogen peroxide (H2O2).


2003 ◽  
Vol 81 (2) ◽  
pp. 156-160 ◽  
Author(s):  
Tian Zhu ◽  
Hou-min Chang ◽  
John F Kadla

A new method for the preparation of peroxymonophosphoric acid (H3PO5) has been developed. It utilizes a biphasic solution to moderate the vigorous reaction between phosphorous pentoxide (P2O5) and hydrogen peroxide (H2O2). P2O5 is suspended in carbon tetrachloride (CCl4), and concentrated H2O2 is slowly added while being vigorously stirred at low temperature. Careful control of the reaction temperature through the slow addition of H2O2 is critical. Using typical preparation conditions (P2O5:H2O2 = 0.5:1, H2O2 70 wt %, 2°C, 120–180 min), ~70% of the H2O2 is effectively converted to H3PO5. Increasing the concentration of H2O2, as well as the mole ratio of P2O5:H2O2, leads to an even higher % conversion of H2O2 to H3PO5. The addition of glacial acetic acid to the P2O5:H2O2 suspension at the end of the 120–180 min reaction (P2O5:H2O2:CH3COOH = 0.5:1:0.3) leads to the formation of peracetic acid in addition to H3PO5, and to an overall increase in the conversion ratio of total peroxy acids based on H2O2 (>95%).Key words: peroxymonophosphoric acid, synthesis, stability, conversion ratio.


1972 ◽  
Vol 55 (1) ◽  
pp. 57-59
Author(s):  
Joel J Thrasher

Abstract A collaborative study has been completed on a new method for light filth in ground coffee. The sample is defatted with chloroform, dried, and boiled in water; isopropanol is added and the sample is boiled again. Light filth is trapped off with mineral oil from a hot solution. The method yields better recoveries of insect fragments and rodent hairs than the official method. Other advantages are less analytical time, cleaner filter papers, and elimination of the use of carbon tetrachloride. It is recommended that the method be adopted as official first action to replace 40.007(b) for the isolation of light filth from ground coffee and that the hydrogen peroxide bleaching technique described earlier be adopted as a procedure to replace the sodium hypochlorite technique described in 40.006.


2010 ◽  
Vol 9 (1) ◽  
pp. 60 ◽  
Author(s):  
Valeria Mozzetti ◽  
Franck Grattepanche ◽  
Déborah Moine ◽  
Bernard Berger ◽  
Enea Rezzonico ◽  
...  

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