Et3B-Induced Radical Addition of Diphenylphosphine Oxide to Unsaturated Compounds.

ChemInform ◽  
2003 ◽  
Vol 34 (47) ◽  
Author(s):  
Patrick Rey ◽  
Jacques Taillades ◽  
Jean Christophe Rossi ◽  
Georges Gros
Keyword(s):  
Radical Addition ◽  
Diphenylphosphine Oxide ◽  
Unsaturated Compounds

Et3B-induced radical addition of diphenylphosphine oxide to unsaturated compounds

2003 ◽  
Vol 44 (32) ◽  
pp. 6169-6171 ◽  
Author(s):  
Patrick Rey ◽  
Jacques Taillades ◽  
Jean Christophe Rossi ◽  
Georges Gros
Keyword(s):  
Radical Addition ◽  
Diphenylphosphine Oxide ◽  
Unsaturated Compounds

The Free Radical Addition of Phosphines to Unsaturated Compounds

1961 ◽  
Vol 26 (12) ◽  
pp. 5138-5145 ◽  
Author(s):  
M. M. RAUHUT ◽  
HELEN A. CURRIER ◽  
A. M. SEMSEL ◽  
V. P. WYSTRACH
Keyword(s):  
Free Radical ◽  
Radical Addition ◽  
Unsaturated Compounds ◽  
Free Radical Addition

α-Csp3–H bond functionalization of simple ethers in radical reactions

Synthesis ◽  
2021 ◽  
Author(s):  
Yanping Feng ◽  
Xiajuan Ye ◽  
Dayun Huang ◽  
Sheng-rong Guo
Keyword(s):  
Radical Addition ◽  
Radical Reactions ◽  
Bond Functionalization ◽  
Unsaturated Compounds ◽  
Metal Catalyzed

The direct α-Csp3-H functionalization of simple ethers has emerged as one of the vital strategies among radical reactions. This review discusses their applications according to the starting materials: (1) reactions with alkenes or alkynes. (2) reactions with other unsaturated compounds. (3) reactions with nucleophilic partners. Mechanisms like radical addition, elimination, oxidation, metal-catalyzed coupling, C-H activation, cyclization and rearrangement will be discussed herein.

Free-radical addition of butyrolactone to unsaturated compounds

1962 ◽  
Vol 11 (1) ◽  
pp. 131-135
Author(s):  
G. I. Nikishin ◽  
G. V. Somov ◽  
Wang Shun-fu ◽  
A. D. Petrov
Keyword(s):  
Free Radical ◽  
Radical Addition ◽  
Unsaturated Compounds ◽  
Free Radical Addition

Free-radical addition of tetrahydrofuranalkanols to unsaturated compounds

1968 ◽  
Vol 17 (7) ◽  
pp. 1507-1510
Author(s):  
V. G. Glukhovtsev ◽  
G. I. Nikishin ◽  
S. S. Spektor ◽  
S. V. Zakharova
Keyword(s):  
Free Radical ◽  
Radical Addition ◽  
Unsaturated Compounds ◽  
Free Radical Addition

Novel regio- and stereoselective phosphonyl radical addition to glycals promoted by Mn(ii)–air: syntheses of 1,2-dideoxy 2-C-diphenylphosphinylglycopyranosides

2014 ◽  
Vol 50 (16) ◽  
pp. 2046-2048 ◽  
Author(s):  
Fuyi Zhang ◽  
Liming Wang ◽  
Cui Zhang ◽  
Yufen Zhao
Keyword(s):  
Radical Reaction ◽  
Radical Addition ◽  
The Novel ◽  
Diphenylphosphine Oxide ◽  
Phosphonyl Radical

The novel Mn(ii)–air promoted radical reaction of diphenylphosphine oxide with various glycals in excellent regio- and stereoselectivities generated 1,2-dideoxy-2-C-diphenylphosphinylglycopyranosides.

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