Transition Metal Complexes of Cyclopentadienyl Ligands

ChemInform ◽  
2003 ◽  
Vol 34 (45) ◽  
Author(s):  
Ian R. Butler
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Cyclopentadienyl Ligands

Stacking interactions of the methylated cyclopentadienyl ligands in the crystal structures of transition metal complexes

2020 ◽  
Vol 76 (2) ◽  
pp. 252-258 ◽  
Author(s):  
Dušan P. Malenov ◽  
Jelena P. Blagojević Filipović ◽  
Snežana D. Zarić
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Transition Metal Complexes ◽  
Electrostatic Potential ◽  
Stacking Interactions ◽  
Cyclopentadienyl Ligands ◽  
Π Interactions ◽  
Structural Database ◽  
Oppositely Charged

In the crystal structures of methylated cyclopentadienyl (Cp) complexes (MeCp, Me4Cp and Me5Cp) deposited in the Cambridge Structural Database, certain orientation types of stacked contacts can be noted as the most frequent. These orientation preferences can be well explained by the matching of oppositely charged regions of electrostatic potential. Parallel displaced stacking, large offset stacking and C—H...π interactions are the dominant interaction types that are responsible for the arrangement in the crystal structures of stacked methylated Cp complexes.

Binuclear transition-metal complexes of cyclophanoid cyclopentadienone and cyclopentadienyl ligands

1989 ◽  
Vol 8 (7) ◽  
pp. 1744-1750 ◽  
Author(s):  
Peter. Jutzi ◽  
Ulrich. Siemeling ◽  
Achim. Mueller ◽  
Hartmut. Boegge
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Cyclopentadienyl Ligands

Indenyl esters as potential electronically modified cyclopentadienyl ligands for transition metal complexes

2002 ◽  
Vol 43 (23) ◽  
pp. 4149-4151 ◽  
Author(s):  
Reko Leino ◽  
Hendrik J.G. Luttikhedde ◽  
Lena Långstedt ◽  
Antti Penninkangas
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Cyclopentadienyl Ligands
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