A Novel Series of Materials Composed of Arrays of Vanadium Oxide Container Molecules, {V18O42(X)} (X: H2O, Cl-, Br-): Synthesis and Characterization of [M2(H2N (CH2)2NH2)5] [{M(H2N (CH2)2NH2)2}2V18O42(X)] ×9H2O (M: Zn, Cd).

ChemInform ◽  
2003 ◽  
Vol 34 (31) ◽  
Author(s):  
M. Ishaque Khan ◽  
Elizabeth Yohannes ◽  
Robert J. Doedens
2007 ◽  
Vol 15 (6) ◽  
pp. 553-559 ◽  
Author(s):  
Jin Kyu Choi ◽  
Yong Woo Kim ◽  
Joo Hwan Koh ◽  
Jong Hak Kim ◽  
Anne M. Mayes

2005 ◽  
Vol 8 (9) ◽  
pp. 841-845 ◽  
Author(s):  
M. Ishaque Khan ◽  
Elizabeth Yohannes ◽  
Robert J. Doedens ◽  
Vladimir O. Golub ◽  
Charles J. O’Connor

1988 ◽  
Vol 121 ◽  
Author(s):  
C. Sanchez ◽  
M. Nabavi ◽  
F. Taulelle

ABSTRACTVanadium oxide gels are synthesized through vanadium oxo-alkoxide hydrolysis condensation processes. Different precursors and hydrolysis conditions lead to different sorts of gels. V0(0Amt)3 hydrolyzed with a large excess of water results in red jammy gels with a layered structure. They exhibit electronic and ionic behavior comparable to vanadium pentoxide gels from inorganic precursors. Hydrolysis of VO(OPrn)3 in an alcoholic medium, leads to orange transparent monolithic gels. They have a highly branched polymeric structure. Controlled hydrolysis of vanadium oxo-alkoxide precursors has the further advantage of giving good adherent thin films.


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