Crystal Structure, Magnetic Behavior and Valence State of Ytterbium in the Yb4Ni10+xGa21-x Phase.

ChemInform ◽  
2003 ◽  
Vol 34 (17) ◽  
Author(s):  
L. Vasylechko ◽  
W. Schnelle ◽  
U. Burkhardt ◽  
R. Ramlau ◽  
R. Niewa ◽  
...  
ChemInform ◽  
2009 ◽  
Vol 40 (35) ◽  
Author(s):  
Volodymyr Svitlyk ◽  
Fan Fei ◽  
Alfred Kracher ◽  
Yurij Mozharivskyj

2000 ◽  
Vol 24 (11) ◽  
pp. 871-876 ◽  
Author(s):  
Amandeep K. Sra ◽  
Guillaume Rombaut ◽  
Fre´de´ric Lahitête ◽  
Ste´phane Golhen ◽  
Lahcène Ouahab ◽  
...  

2018 ◽  
Vol 15 (29) ◽  
pp. 228-233
Author(s):  
J. A. FLORES-CRUZ ◽  
G. E. DELGADO ◽  
J. E. CONTRERAS ◽  
M. QUINTERO ◽  
L. NIEVES ◽  
...  

The chalcogenide compound CuNbGaSe3, belonging to the system I-II-III-VI3, has been investigated by means of X-ray powder diffraction and its crystal structure has been refined by the Rietveld method.This is a material of the semiconductor type, which improves the properties of a simple semiconductor like CuGaSe2 because it ads spintronic applications due to its magnetic behavior. The powder pattern was composed by 94.2% of the principal phase CuNbGaSe3 and 5.8% of the secondary phase Cu0.667NbSe2. This material crystallizes with a CuFeInSe3-type structure in the tetragonal space group P4 2c (Nº 112), unit cell parameters a = 5.6199(4) Å, c = 11.0275(2) Å, V = 348.28(4) Å3, with a normal adamantane-structure where occurs a degradation of symmetry from the chalcopyrite structure I4 2d to a related structure P4 2c.


1996 ◽  
Vol 35 (1) ◽  
pp. 168-172 ◽  
Author(s):  
José A. Ayllón ◽  
Isabel C. Santos ◽  
Rui T. Henriques ◽  
Manuel Almeida ◽  
Luís Alcácer ◽  
...  

1988 ◽  
Vol 43 (10) ◽  
pp. 1256-1262 ◽  
Author(s):  
Hans-Friedrich Klein ◽  
Goetz Lull ◽  
Birgit Rodenhäuser ◽  
Gerhard Cordier ◽  
Helmut Paulus

Mononuclear cobalt(o) complexes containing olefin and trimethylphosphane ligands Co(olefin)(PMe3)3 (olefin = C2H4 (1), C3H6 (2), cyclopentene (3), trans-1,2-diphenylethene (4), tetrafluorobenzo-bicyclo-(2.2.2)-octadiene (5)), are obtained from CoCl2 by reaction with magnesium in the presence of the ligands or by substitution of 3 with olefin. X-ray crystal structure determinations of 4 and 5 show a distorted tetrahedral arrangement of ligands around the cobalt atom. Chemical and spectroscopic properties are consistent with a paramagnetic valence state of the compounds in solution. By reaction with carbon monoxide a dicobalt complex is formed, while azobenzene gives paramagnetic Co(N2Ph2)(PMe3)2.


ChemInform ◽  
2008 ◽  
Vol 39 (4) ◽  
Author(s):  
R. M. Pinacca ◽  
M. C. Viola ◽  
J. C. Pedregosa ◽  
M. J. Martinez-Lope ◽  
R. E. Carbonio ◽  
...  

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