In situ Alcohol Oxidation—Wittig Reactions Using N-Methoxy-N-methyl-2-(triphenylphosphoranylidine)acetamide: Application to the Synthesis of a Novel Analogue of 5-Oxo-eicosatetraenoic Acid.

ChemInform ◽  
2003 ◽  
Vol 34 (12) ◽  
Author(s):  
Leonie Blackburn ◽  
Hisashi Kanno ◽  
Richard J. K. Taylor
Keyword(s):  
Alcohol Oxidation ◽  
Eicosatetraenoic Acid ◽  
Wittig Reactions

In situ alcohol oxidation-Wittig reactions

1998 ◽  
Vol 39 (22) ◽  
pp. 3815-3818 ◽  
Author(s):  
Xudong Wei ◽  
Richard J.K Taylor
Keyword(s):  
Alcohol Oxidation ◽  
Wittig Reactions

ChemInform Abstract: In situ Aerobic Alcohol Oxidation-Wittig Reactions.

ChemInform ◽  
2010 ◽  
Vol 33 (16) ◽  
pp. no-no ◽  
Author(s):  
Guncheol Kim ◽  
Don Gyu Lee ◽  
Sukbok Chang
Keyword(s):  
Alcohol Oxidation ◽  
Wittig Reactions

ChemInform Abstract: In situ Alcohol Oxidation-Wittig Reactions Using Non-stabilized Phosphoranes.

ChemInform ◽  
2010 ◽  
Vol 33 (26) ◽  
pp. no-no
Author(s):  
Leonie Blackburn ◽  
Chengxin Pei ◽  
Richard J. K. Taylor
Keyword(s):  
Alcohol Oxidation ◽  
Wittig Reactions

ChemInform Abstract: In situ Alcohol Oxidation-Wittig Reactions.

ChemInform ◽  
2010 ◽  
Vol 29 (33) ◽  
pp. no-no
Author(s):  
X. WEI ◽  
R. J. K. TAYLOR
Keyword(s):  
Alcohol Oxidation ◽  
Wittig Reactions

In Situ Alcohol Oxidation-Wittig Reactions Using Non-stabilised Phosphoranes

Synlett ◽  
2002 ◽  
Vol 2002 (02) ◽  
pp. 0215-0218 ◽  
Author(s):  
Leonie Blackburn ◽  
Chengxin Pei ◽  
Richard J. K. Taylor
Keyword(s):  
Alcohol Oxidation ◽  
Wittig Reactions

scholarly journals Biomimetic Cu/Nitroxyl Catalyst Systems for Selective Alcohol Oxidation

Catalysts ◽  
2019 ◽  
Vol 9 (5) ◽  
pp. 395 ◽  
Author(s):  
Lindie Marais ◽  
Andrew John Swarts
Keyword(s):  
Active Sites ◽  
Alcohol Oxidation ◽  
Galactose Oxidase ◽  
Co Catalyst ◽  
Co Catalysts ◽  
Mechanistic Pathway ◽  
Oxidation Of Alcohols ◽  
Catalyst Systems ◽  
Carbonyl Products

The oxidation of alcohols to the corresponding carbonyl products is an important organic transformation and the products are used in a variety of applications. The development of catalytic methods for selective alcohol oxidation have garnered significant attention in an attempt to find a more sustainable method without any limitations. Copper, in combination with 2,2,6,6-tetramethyl-1-piperidine N-oxyl (TEMPO) and supported by organic ligands, have emerged as the most effective catalysts for selective alcohol oxidation and these catalyst systems are frequently compared to galactose oxidase (GOase). The efficiency of GOase has led to extensive research to mimic the active sites of these enzymes, leading to a variety of Cu/TEMPO· catalyst systems being reported over the years. The mechanistic pathway by which Cu/TEMPO· catalyst systems operate has been investigated by several research groups, which led to partially contradicting mechanistic description. Due to the disadvantages and limitations of employing TEMPO· as co-catalyst, alternative nitroxyl radicals or in situ formed radicals, as co-catalysts, have been successfully evaluated in alcohol oxidation. Herein we discuss the development and mechanistic elucidation of Cu/TEMPO· catalyst systems as biomimetic alcohol oxidation catalysts.

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