Reaction Between Isocyanides and Dialkyl Acetylenedicarboxylates in the Presence of 3-Methylcyclopentane-1,2,4-trione. One-Pot Diastereoselective Synthesis of Tetrahydrocyclopenta[b]pyran Derivatives.

ChemInform ◽  
2003 ◽  
Vol 34 (11) ◽  
Author(s):  
Issa Yavari ◽  
Mehdi Adib ◽  
Mohammad H. Sayahi
1999 ◽  
Vol 23 (6) ◽  
pp. 368-369
Author(s):  
Issa Yavari ◽  
Abbas Ali Esmaili ◽  
Sakineh Asghari ◽  
Hamid Reza Bijanzadeh

The highly reactive 1:1 intermediate produced in the reaction between tert-butyl isocyanide and dialkyl acetylenedicarboxylates is trapped by dialkyl 2-bromomalonates to yield the title compounds in fairly high yields.


Author(s):  
Mohammad Bagher Teimouri ◽  
Zahra Mokhtare ◽  
Hamid Reza Khavasi

Three new chemical bonds and three stereogenic centres and one heterocyclic ring were assembled stereoselectively in a convenient high atom-economy one-pot operation.


2012 ◽  
Vol 9 (4) ◽  
pp. 2239-2244 ◽  
Author(s):  
Hossein Anaraki-Ardakani ◽  
Maziar Noei ◽  
Mina Karbalaei-Harofteh ◽  
Shahab Zomorodbakhsh

A new and efficient one-pot synthesis of polysubstituted pyrrole derivatives by three-component reaction between dialkyl acetylenedicarboxylates, triphenylphosphine, 2-aminopyridin derivatives in the presence of arylglyoxals is described. The reactions were performed in dichloromethane at room temperature and neutral conditions and afforded high yields of products.


ChemInform ◽  
2008 ◽  
Vol 39 (38) ◽  
Author(s):  
J. S. Yadav ◽  
B. V. Subba Reddy ◽  
S. Aravind ◽  
G. G. K. S. Narayana Kumar ◽  
C. Madhavi ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document