Homogeneous Controlled Free Radical Polymerization in Aqueous Media

ChemInform ◽  
2003 ◽  
Vol 34 (1) ◽  
pp. no-no ◽  
Author(s):  
Andrew B. Lowe ◽  
Charles L. McCormick
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Aqueous Media ◽  
Free Radical Polymerization

Enzyme-mediated free radical polymerization of acrylamide in deep eutectic solvents

RSC Advances ◽  
2016 ◽  
Vol 6 (16) ◽  
pp. 13072-13079 ◽  
Author(s):  
R. J. Sánchez-Leija ◽  
J. R. Torres-Lubián ◽  
A. Reséndiz-Rubio ◽  
G. Luna-Bárcenas ◽  
J. D. Mota-Morales
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Aqueous Media ◽  
Free Radical Polymerization ◽  
Deep Eutectic Solvents

The enzyme-mediated free radical polymerization of acrylamide was performed in nearly non-aqueous DES, which allowed the exploration of higher and lower temperatures that in aqueous media.

Homogeneous Controlled Free Radical Polymerization in Aqueous Media

2002 ◽  
Vol 55 (7) ◽  
pp. 367 ◽  
Author(s):  
A. B. Lowe ◽  
C. L. McCormick
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Aqueous Media ◽  
Free Radical Polymerization ◽  
Specific Reference ◽  
Controlled Polymerization ◽  
Stable Free Radical ◽  
Water Solvent ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

The ability to conduct controlled radical polymerizations (CRP) in homogeneous aqueous media is discussed. Three main techniques, namely stable free radical polymerization (SFRP), with an emphasis on nitroxide-mediated polymerization (NMP), atom transfer radical polymerization (ATRP) and reversible addition-fragmentation chain transfer polymerization (RAFT) are examined. No examples exist of homogeneous aqueous NMP polymerization, but mixed water/solvent systems are discussed with specific reference to the NMP of sodium 4-styrenesulfonate. Aqueous ATRP is possible, although monomer choice is limited to methacrylates and certain styrenics. Finally, homogeneous aqueous RAFT polymerizations are examined. We demonstrate the greater versatility of this technique, at least in terms of monomer variety, by discussing the controlled polymerization of charged and neutral acrylamido monomers and of a series of ionic styrenic monomers. Many of these monomers cannot/have not been polymerized by either NMP or ATRP.

Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate

2018 ◽  
Vol 8 (3) ◽  
pp. 585-594
Author(s):  
Khdbudin Mulani ◽  
Ravindra Ghorpade ◽  
Surendra Ponrathnam ◽  
Nayaku Chavan ◽  
Kamini Donde
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Isothermal Kinetics ◽  
Kinetics Of

Oxygen-Initiated Free-Radical Polymerization of Alkyl Acrylates at High Temperatures

2021 ◽  
Author(s):  
Shi Liu ◽  
Lauren Chua ◽  
Ahmad Arabi Shamsabadi ◽  
Patrick Corcoran ◽  
Abhirup Patra ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
High Temperatures ◽  
Free Radical Polymerization ◽  
Alkyl Acrylates
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