ChemInform Abstract: Selenium Catalyzed Oxidations with Aqueous Hydrogen Peroxide. Part 3. Oxidation of Carbonyl Compounds under Mono/Bi/Triphasic Conditions.

ChemInform ◽  
2010 ◽  
Vol 33 (39) ◽  
pp. no-no
Author(s):  
Gerd-Jan ten Brink ◽  
J. Martijn Vis ◽  
Isabel W. C. E. Arends ◽  
Roger A. Sheldon
Keyword(s):  
Hydrogen Peroxide ◽  
Carbonyl Compounds ◽  
Aqueous Hydrogen Peroxide

Selenium catalysed oxidations with aqueous hydrogen peroxide. Part 3: Oxidation of carbonyl compounds under mono/bi/triphasic conditions

Tetrahedron ◽  
2002 ◽  
Vol 58 (20) ◽  
pp. 3977-3983 ◽  
Author(s):  
Gerd-Jan ten Brink ◽  
J.Martijn Vis ◽  
Isabel W.C.E Arends ◽  
Roger A Sheldon
Keyword(s):  
Hydrogen Peroxide ◽  
Carbonyl Compounds ◽  
Aqueous Hydrogen Peroxide

Epoxidation of electron-deficient α,β-unsaturated carbonyl compounds over Keggin heteropoly compounds with aqueous H2O2

2005 ◽  
Vol 2005 (11) ◽  
pp. 716-718 ◽  
Author(s):  
Qiang Gao ◽  
Yong Ding ◽  
Haitao Liu ◽  
Jishuan Suo
Keyword(s):  
Hydrogen Peroxide ◽  
Carbonyl Compounds ◽  
Catalytic Performance ◽  
Heteropoly Compounds ◽  
Aqueous Hydrogen Peroxide

The epoxidation of a variety of electron-deficient α,β-unsaturated carbonyl compounds has been studied using a series of heteropoly compounds and aqueous hydrogen peroxide in acetonitrile. Among the heteropoly compounds investigated, (CTP)3VMo12O40 showed the highest catalytic performance for the epoxidation of these compounds.

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

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