ChemInform Abstract: Catalytic Chain Transfer in Free-Radical Polymerizations

ChemInform ◽  
2010 ◽  
Vol 33 (15) ◽  
pp. no-no
Author(s):  
Alexei A. Gridnev ◽  
Steven D. Ittel
Keyword(s):  
Free Radical ◽  
Chain Transfer ◽  
Catalytic Chain Transfer ◽  
Radical Polymerizations

Catalytic Chain Transfer in Free-Radical Polymerizations

2001 ◽  
Vol 101 (12) ◽  
pp. 3611-3660 ◽  
Author(s):  
Alexei A. Gridnev ◽  
Steven D. Ittel
Keyword(s):  
Free Radical ◽  
Chain Transfer ◽  
Catalytic Chain Transfer ◽  
Radical Polymerizations

New chain transfer agents for free radical polymerizations

1991 ◽  
Vol 26 (4) ◽  
pp. 239-244 ◽  
Author(s):  
Gordon F. Meijs ◽  
Ezio Rizzardo ◽  
Tam P. T. Le
Keyword(s):  
Free Radical ◽  
Chain Transfer ◽  
Radical Polymerizations ◽  
Transfer Agents

Catalytic Chain Transfer Polymerization: an Overview

2002 ◽  
Vol 55 (7) ◽  
pp. 381 ◽  
Author(s):  
J. P. A. Heuts ◽  
G. E. Roberts ◽  
J. D. Biasutti
Keyword(s):  
Free Radical ◽  
Transition Metal ◽  
Metal Complexes ◽  
Radical Polymerization ◽  
Transition Metal Complexes ◽  
Chain Transfer ◽  
Free Radical Polymerization ◽  
Catalytic Chain Transfer ◽  
Mechanistic Understanding ◽  
Chain Transfer Polymerization

Catalytic chain transfer polymerization is a very efficient and versatile free-radical polymerization technique for the synthesis of functional macromonomers. The process is based on the ability of certain transition metal complexes, most notably of low-spin CoII complexes such as cobaloximes, to catalyse the chain transfer to monomer reaction. A brief overview is given of the applications and the mechanistic understanding of catalytic chain transfer polymerization.

When Mayo falls short (Ctr ≫ 1): the use of cumulative chain length distribution data in the determination of chain transfer constants (Ctr) for radical polymerizations

2020 ◽  
Vol 11 (26) ◽  
pp. 4281-4289
Author(s):  
Matt K. Donald ◽  
Stefan A. F. Bon
Keyword(s):  
Molecular Weight ◽  
Free Radical ◽  
Chain Length ◽  
Weight Distribution ◽  
Chain Transfer ◽  
Length Distribution ◽  
Distribution Data ◽  
Chain Length Distribution ◽  
Radical Polymerizations

A method to determine chain transfer constants in free radical polymerizations that are >1 using molecular weight distribution data.

Catalytic Chain Transfer Polymerization to Functional Reactive End Groups for Controlled Free Radical Growth

2020 ◽  
Vol 53 (7) ◽  
pp. 2362-2368
Author(s):  
Sonja M. Stadler ◽  
Inigo Göttker-Schnetmann ◽  
Amelie S. Fuchs ◽  
Stephan R. R. Fischer ◽  
Stefan Mecking
Keyword(s):  
Free Radical ◽  
Chain Transfer ◽  
End Groups ◽  
Catalytic Chain Transfer ◽  
Chain Transfer Polymerization
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