ChemInform Abstract: Asymmetric Synthesis of N-Diphenylphosphinoylamines by Solvent-Free Enantioselective Addition of Dialkylzincs to N-Diphenylphosphinoylimines.

ChemInform ◽  
2010 ◽  
Vol 33 (11) ◽  
pp. no-no
Author(s):  
Itaru Sato ◽  
Ryo Kodaka ◽  
Kenso Soai
2001 ◽  
Vol 73 (2) ◽  
pp. 325-329 ◽  
Author(s):  
Marco Bandini ◽  
Pier Giorgio Cozzi ◽  
Achille Umani-Ronchi

Different types of chiral "privileged" ligands 1 and 2 in promoting enantioselective addition of allylating agents to aliphatic and aromatic aldehydes are described. Here, a new concept in the asymmetric allylation reaction is presented. Redox [Cr (Salen) ] mediated addition of allyl halides to carbonyl compounds is described, and mechanistic investigations are discussed. These results open access to the fascinating area of the catalytic redox processes mediated by metallo-Salen complexes.


ChemInform ◽  
2001 ◽  
Vol 32 (12) ◽  
pp. no-no
Author(s):  
Itaru Sato ◽  
Takahiro Saito ◽  
Kenso Soai

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