ChemInform Abstract: Efficient Intramolecular General Acid Catalysis: A Preview from a Crystal Structure.

ChemInform ◽

10.1002/chin.200211010 ◽

2010 ◽

Vol 33 (11) ◽

pp. no-no

Author(s):

Andrew D. Bond ◽

Anthony J. Kirby ◽

Encina Rodriguez

Keyword(s):

Crystal Structure ◽

Acid Catalysis ◽

General Acid

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Faculty Opinions recommendation of Leaving group activation by aromatic stacking: an alternative to general acid catalysis.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1019017.289706 ◽

2005 ◽

Author(s):

Daniel Herschlag

Keyword(s):

Acid Catalysis ◽

Aromatic Stacking ◽

General Acid ◽

Leaving Group

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Faculty Opinions recommendation of Leaving group activation by aromatic stacking: an alternative to general acid catalysis.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1019017.214544 ◽

2004 ◽

Author(s):

Barry Stoddard

Keyword(s):

Acid Catalysis ◽

Aromatic Stacking ◽

General Acid ◽

Leaving Group

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Faculty Opinions recommendation of General acid catalysis by the hepatitis delta virus ribozyme.

Faculty Opinions – Post-Publication Peer Review of the Biomedical Literature ◽

10.3410/f.1030315.323505 ◽

2005 ◽

Author(s):

David MJ Lilley

Keyword(s):

Hepatitis Delta Virus ◽

Acid Catalysis ◽

Hepatitis Delta ◽

Hepatitis Delta Virus Ribozyme ◽

General Acid ◽

Delta Virus

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Efficient intramolecular general acid catalysis of the hydrolysis of a dialkyl acetal

Chemical Communications ◽

10.1039/cc9960002355 ◽

1996 ◽

pp. 2355 ◽

Cited By ~ 1

Author(s):

Christopher J. Brown ◽

Anthony J. Kirby

Keyword(s):

Acid Catalysis ◽

General Acid ◽

Hydrolysis Of

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General acid catalysis in moderately concentrated aqueous sulphuric acid

Discussions of the Faraday Society ◽

10.1039/df9653900075 ◽

1965 ◽

Vol 39 ◽

pp. 75 ◽

Cited By ~ 18

Author(s):

A. J. Kresge ◽

L. E. Hakka ◽

S. Mylonakis ◽

Y. Sato

Keyword(s):

Sulphuric Acid ◽

Acid Catalysis ◽

General Acid

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Calculations of enzymic reactions: calculations of pKa, proton transfer reactions, and general acid catalysis reactions in enzymes

Biochemistry ◽

10.1021/bi00514a028 ◽

1981 ◽

Vol 20 (11) ◽

pp. 3167-3177 ◽

Cited By ~ 228

Author(s):

Arieh Warshel

Keyword(s):

Proton Transfer ◽

Acid Catalysis ◽

Transfer Reactions ◽

General Acid ◽

Proton Transfer Reactions

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Kinetic isotope effects and aliphatic diazo-compounds. Part V. Secondary isotope effects in general acid catalysis

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29720002203 ◽

1972 ◽

pp. 2203 ◽

Cited By ~ 5

Author(s):

W. J. Albery ◽

J. R. Bridgeland ◽

J. S. Curran

Keyword(s):

Acid Catalysis ◽

Isotope Effects ◽

Kinetic Isotope Effects ◽

Diazo Compounds ◽

Kinetic Isotope ◽

General Acid

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Prostacyclin: evidence that intramolecular general-acid catalysis by its carboxylic acid group is responsible for the extra hydrolytic lability

Journal of the American Chemical Society ◽

10.1021/ja00274a057 ◽

1986 ◽

Vol 108 (14) ◽

pp. 4192-4196 ◽

Cited By ~ 12

Author(s):

Y. Chiang ◽

M. J. Cho ◽

B. A. Euser ◽

A. Jerry. Kresge

Keyword(s):

Carboxylic Acid ◽

Acid Catalysis ◽

Acid Group ◽

Carboxylic Acid Group ◽

General Acid

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general acid catalysis

IUPAC Compendium of Chemical Terminology ◽

10.1351/goldbook.g02609 ◽

2008 ◽

Keyword(s):

Acid Catalysis ◽

General Acid

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A Dendralenic C–H Acid

Synlett ◽

10.1055/s-0037-1612246 ◽

2019 ◽

Vol 30 (04) ◽

pp. 433-436 ◽

Cited By ~ 3

Author(s):

Denis Höfler ◽

Richard Goddard ◽

Nils Nöthling ◽

Benjamin List

Keyword(s):

Crystal Structure ◽

Acid Catalysis ◽

Bronsted Acid ◽

Brønsted Acid ◽

Design And Synthesis ◽

Brönsted Acid ◽

Bronsted Acid Catalysis

The design and synthesis of a strong, dendralenic C–H acid is described. Crystal structure analyses confirm the proposed structure. Despite the moderate stability of our motif, an application to Brønsted acid catalysis has been explored.

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