ChemInform Abstract: Oxidation of Alcohols and Primary Aliphatic Amines to Carbonyl Compounds Using Sodium Hypochlorite Adsorbed on Montmorillonite K10.

ChemInform ◽  
2000 ◽  
Vol 31 (44) ◽  
pp. no-no
Author(s):  
Mohammed M. Hashemi ◽  
Yousef A. Beni
Keyword(s):  
Sodium Hypochlorite ◽  
Carbonyl Compounds ◽  
Aliphatic Amines ◽  
Montmorillonite K10 ◽  
Oxidation Of Alcohols ◽  
Primary Aliphatic Amines

Oxidation of Benzylic Alcohols to Carbonyl Compounds with Hydrogen Peroxide Catalysed by Manganeses Chloride Supported on Montmorillonite K10

2005 ◽  
Vol 2005 (8) ◽  
pp. 484-485 ◽  
Author(s):  
Mohammed M. Hashemi ◽  
Behzad Khalili ◽  
Bagher Eftekhari-sis
Keyword(s):  
Hydrogen Peroxide ◽  
Carbonyl Compounds ◽  
Benzylic Alcohols ◽  
Montmorillonite K10 ◽  
Oxidation Of Alcohols

Manganeses(II) chloride supported on montmorillonite K10 was found to be an efficient catalysts for the oxidation of alcohols to carbonyl compounds with hydrogen peroxide as oxidant.

A simple biomimetic protocol for the oxidation of alcohols with sodium hypochlorite in the presence of β-cyclodextrin in water

2004 ◽  
Vol 82 (7) ◽  
pp. 1230-1233 ◽  
Author(s):  
K Surendra ◽  
N Srilakshmi Krishnaveni ◽  
K Rama Rao
Keyword(s):  
Sodium Hypochlorite ◽  
Carbonyl Compounds ◽  
Room Temperature ◽  
Water As Solvent ◽  
Oxidation Of Alcohols

A simple and efficient protocol, which is inexpensive, convenient, clean, and facile, for oxidation of alcohols to carbonyl compounds has been developed using sodium hypochlorite in the presence of β-cyclodextrin with water as solvent. A series of alcohols were oxidized at room temperature in excellent yields.Key words: oxidation, alcohols, sodium hypochlorite, KBr, β-cyclodextrin, biomimetic, water.

Exogenous Directing Group Free, Ligand-Enabled gamma-C(sp3)–H Arylation of Free Primary Aliphatic Amines and α-Amino Esters

2019 ◽  
Author(s):  
Yongzheng Ding ◽  
Shuai Fan ◽  
Xiaoxi Chen ◽  
yuzhen gao ◽  
Gang Li
Keyword(s):  
Amino Acids ◽  
Large Scale ◽  
Free Ligand ◽  
Aliphatic Amines ◽  
Rapid Synthesis ◽  
Amino Esters ◽  
Directing Group ◽  
Large Scale Synthesis ◽  
Primary Aliphatic Amines

A Pdᴵᴵ-catalyzed, ligand-enabled gamma-C(sp3)–H arylation of free primary aliphatic amines and amino esters without using an exogenous directing group is reported. This reaction is compatible with unhindered free aliphatic amines, and it is also be applicable to the rapid synthesis of biologically and synthetically valuable unnatural α-amino acids. Large scale synthesis is also feasible using this method.<br>

Pd‐Catalyzed Regio‐ and Stereoselective sp 3 C−H Arylation of Primary Aliphatic Amines: Mechanistic Studies and Synthetic Applications

2021 ◽  
Vol 2021 (7) ◽  
pp. 1136-1145
Author(s):  
Hyeonbin Ha ◽  
Ho Jeong Choi ◽  
Hahyoun Park ◽  
Yunyeong Gwon ◽  
Jiin Lee ◽  
...  
Keyword(s):  
Aliphatic Amines ◽  
Mechanistic Studies ◽  
Primary Aliphatic Amines

Oxidation of primary aliphatic amines with sodium perborate

1989 ◽  
Vol 30 (47) ◽  
pp. 6495-6496 ◽  
Author(s):  
Walter W Zajac ◽  
Michael G Darcy ◽  
Amador P Subong ◽  
John H Buzby
Keyword(s):  
Aliphatic Amines ◽  
Sodium Perborate ◽  
Primary Aliphatic Amines

N-tert-Butylbenzenesulfenamide-catalyzed oxidation of alcohols to the corresponding carbonyl compounds with N-chlorosuccinimide

Tetrahedron ◽  
2003 ◽  
Vol 59 (35) ◽  
pp. 6739-6750 ◽  
Author(s):  
Jun-ichi Matsuo ◽  
Daisuke Iida ◽  
Hiroyuki Yamanaka ◽  
Teruaki Mukaiyama
Keyword(s):  
Carbonyl Compounds ◽  
Oxidation Of Alcohols ◽  
Catalyzed Oxidation

Chemoselective C−H Oxidation of Alcohols to Carbonyl Compounds with Iodosobenzene Catalyzed by (Salen)chromium Complex

2000 ◽  
Vol 65 (7) ◽  
pp. 1915-1918 ◽  
Author(s):  
Waldemar Adam ◽  
Feyissa Gadissa Gelalcha ◽  
Chantu R. Saha-Möller ◽  
Veit R. Stegmann
Keyword(s):  
Carbonyl Compounds ◽  
Chromium Complex ◽  
Oxidation Of Alcohols
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