ChemInform Abstract: Hydrochloric Acid Catalysis of N-Bromosuccinimide (NBS) Mediated Nuclear Aromatic Brominations in Acetone.

ChemInform ◽  
2000 ◽  
Vol 31 (40) ◽  
pp. no-no
Author(s):  
Brad Andersh ◽  
Drew L. Murphy ◽  
Ryan J. Olson
2009 ◽  
Vol 201 (2-3) ◽  
pp. 214-221 ◽  
Author(s):  
P.P. Lima ◽  
R.A.S. Ferreira ◽  
S.A. Júnior ◽  
O.L. Malta ◽  
L.D. Carlos

2000 ◽  
Vol 30 (12) ◽  
pp. 2091-2098 ◽  
Author(s):  
Brad Andersh ◽  
Drew L. Murphy ◽  
Ryan J. Olson

2009 ◽  
Vol 87 (4) ◽  
pp. 539-543 ◽  
Author(s):  
Yih-Huang Hsieh ◽  
Noham Weinberg ◽  
Saul Wolfe

The neutral hydrolysis of methyl acetate and catalysis of the reaction by the acetic acid product have been studied in the temperature range 90–110 °C. Extrapolated to 25 °C, the rate constants are 0.17 × 10−8 s–1 for the uncatalyzed reaction and 1.4 × 10−4 (mol/L)–1s–1 for the catalyzed reaction. The acid catalysis is specific not general: at 90 °C the rate constants for hydrochloric acid catalysis and catalysis by ionized acetic acid are the same as the rate constant, kH = 1.4 × 10−2 (mol/L)–1s–1, determined in the neutral reaction.


2015 ◽  
Vol 17 (10) ◽  
pp. 4725-4735 ◽  
Author(s):  
T. Dallas Swift ◽  
Hannah Nguyen ◽  
Andrzej Anderko ◽  
Vladimiros Nikolakis ◽  
Dionisios G. Vlachos

Optimizing the concentrations of Lewis and Brønsted acids maximizes the 5-hydroxymethylfurfural yield from glucose in a single pot.


Author(s):  
W. H. Zucker ◽  
R. G. Mason

Platelet adhesion initiates platelet aggregation and is an important component of the hemostatic process. Since the development of a new form of collagen as a topical hemostatic agent is of both basic and clinical interest, an ultrastructural and hematologic study of the interaction of platelets with the microcrystalline collagen preparation was undertaken.In this study, whole blood anticoagulated with EDTA was used in order to inhibit aggregation and permit study of platelet adhesion to collagen as an isolated event. The microcrystalline collagen was prepared from bovine dermal corium; milling was with sharp blades. The preparation consists of partial hydrochloric acid amine collagen salts and retains much of the fibrillar morphology of native collagen.


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