ChemInform Abstract: Reactions of Complex Ligands. Part 81. Chromium Complex Catalyzed Synthesis of Spirocyclopropanes from Diaryl Diazo Compounds - Direct NMR-Spectroscopic Observation of a Carbene Complex Intermediate.

ChemInform ◽  
2010 ◽  
Vol 29 (38) ◽  
pp. no-no
Author(s):  
J. PFEIFFER ◽  
M. NIEGER ◽  
K. H. DOETZ
Keyword(s):  
Spectroscopic Observation ◽  
Diazo Compounds ◽  
Chromium Complex ◽  
Carbene Complex

Confocal and fluorescence lifetime imaging sheds light on the fate of a pyrene-tagged carbon monoxide-releasing Fischer carbene chromium complex

2015 ◽  
Vol 44 (11) ◽  
pp. 4957-4962 ◽  
Author(s):  
Rory L. Arrowsmith ◽  
Anthony J. Atkin ◽  
Stanley W. Botchway ◽  
Ian J. S. Fairlamb ◽  
Jason M. Lynam ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Fluorescence Lifetime ◽  
Fluorescence Lifetime Imaging ◽  
Chromium Complex ◽  
Carbene Complex ◽  
Fischer Carbene ◽  
Lifetime Imaging

The synthesis of a new pyrene-containing Fischer carbene complex is described.

On the Reactivity of mRNA Caps: C-H Oxidative Addition of 7-Methylguanosine to Pt(0)

2019 ◽  
Author(s):  
Maria Ines Leitao ◽  
Carmen Gonzalez ◽  
Zuzanna Filipiak ◽  
Ana Petronilho
Keyword(s):  
Oxidative Addition ◽  
Carbene Complex ◽  
Proton Loss

<p>7-methylguanosine, the so-called mRNA cap 0 bears a very labile C8-H bond, due to the formation of an ylide/N-heterocyclic carbene, upon proton loss. The reaction of 7-methylguanosine with Pt(PPh3)4, via C-H oxidative addition, yields a hydrido–PtII carbene complex and this reactivity can be extrapolated to 7,9-dimethylguanine. </p>

New catalysts for the reduction of aromatic diazo compounds by alcohols to hydrocarbons

1983 ◽  
Vol 32 (4) ◽  
pp. 858-861 ◽  
Author(s):  
V. S. Lenenko ◽  
A. P. Borisov ◽  
V. D. Makhaev ◽  
E. I. Mysov ◽  
V. B. Shur ◽  
...  
Keyword(s):  
Diazo Compounds

scholarly journals Estimation of bulk permittivity of the Moon’s surface using Lunar Radar Sounder on-board Selenological and Engineering Explorer

2020 ◽  
Vol 72 (1) ◽  
Author(s):  
Keigo Hongo ◽  
Hiroaki Toh ◽  
Atsushi Kumamoto
Keyword(s):  
Electrical Conductivity ◽  
Physical Properties ◽  
Titanium Content ◽  
Spectroscopic Observation ◽  
Lunar Rock ◽  
Almost All ◽  
Mare Serenitatis ◽  
Radar Sounder ◽  
Lunar Maria ◽  
Regolith Layer

Abstract Site-dependent bulk permittivities of the lunar uppermost media with thicknesses of tens to hundreds meters were estimated based on the data from Lunar Radar Sounder onboard the Selenological and Engineering Explorer (SELENE). It succeeded in sounding almost all over the Moon’s surface in a frequency range around 5 MHz to detect subsurface reflectors beneath several lunar maria. However, it is necessary to estimate the permittivity of the surface regolith of the Moon in order to determine the actual depths to those reflectors instead of apparent depths assuming a speed of light in the vacuum. In this study, we determined site-dependent bulk permittivities by two-layer models consisting of a surface regolith layer over a half-space with uniform, but different physical properties from the layer above. Those models consider the electrical conductivity as well as the permittivity, whose trade-off was resolved by utilizing the correlation between iron–titanium content and measured physical properties of lunar rock samples. Distribution of the iron–titanium content on the Moon’s surface had already been derived by spectroscopic observation from SELENE as well. Four lunar maria, Mare Serenitatis, Oceanus Procellarum, Mare Imbrium, and Mare Crisium, were selected as regions of evident reflectors, where we estimated the following four physical properties of each layer, i.e., bulk permittivity, porosity, loss tangent and electrical conductivity to conclude the actual depths of the reflectors are approximately 200 m on average. The bulk permittivity ranges from 2.96 at Mare Imbrium to 6.37 at Oceanus Procellarum, whereas the porosity takes the values between 1.8 and 41.1% in the respective maria. It was found that although the bulk permittivity of the four lunar maria differs from a mare to a mare, it shows a good correlation with their composition, viz., their iron–titanium content.

Sign in / Sign up

Export Citation Format

Share Document