ChemInform Abstract: Intramolecular Amidoalkylation of N-Alkylidene-N′-arylureas Activated by Trifluoromethyl Groups. Synthetic Access to 4-Trifluoromethyl-2(1H,3H,4H)-quinazolones.

ChemInform ◽  
2010 ◽  
Vol 29 (33) ◽  
pp. no-no
Author(s):  
M. V. VOVK ◽  
V. I. DOROKHOV ◽  
A. V. BOL'BUT
Keyword(s):  
Intramolecular Amidoalkylation ◽  
Trifluoromethyl Groups

The novel cyclopropapyrroloindole(CPI) bisalkylators bearing methoxycarbonyl and trifluoromethyl groups

1998 ◽  
Vol 8 (11) ◽  
pp. 1387-1390 ◽  
Author(s):  
Yasumichi Fukuda ◽  
Hirosuke Furuta ◽  
Yoshie Kusama ◽  
Hiroyuki Ebisu ◽  
Yasuo Oomori ◽  
...  
Keyword(s):  
The Novel ◽  
Trifluoromethyl Groups

scholarly journals Cs[Tf2N]: a second polymorph with a layered structure

2018 ◽  
Vol 74 (4) ◽  
pp. 551-554
Author(s):  
Jared T. Stritzinger ◽  
Janelle E. Droessler ◽  
Brian L. Scott ◽  
George S. Goff
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Opposite Direction ◽  
Layered Structure ◽  
Layer Structure ◽  
Structural Determination ◽  
Polar Surface ◽  
Trifluoromethyl Groups

The structural determination of the ionic liquid, caesium bis[(trifluoromethyl)sulfonyl]imide or poly[[μ4-bis[(trifluoromethyl)sulfonyl]imido]caesium(I)], Cs[N(SO2CF3)2] or Cs[Tf2N], reveals a second polymorph that also crystallizes in a layer structure possessing monoclinic P21/c symmetry at 120 K instead of C2/c for the known polymorph [Xue et al. (2002). Solid State Sci. 4, 1535–1545]. The caesium ions in the cationic layers are coordinated by the sulfonyl groups of the bistriflimide molecules from anion layers while the trifluoromethyl groups are oriented in the opposite direction, forming a non-polar surface separating the layers. The layer direction is (100).

Intramolecular Diels-Alder reactions of furan derivatives: Steric and electronic effects of trifluoromethyl groups

1992 ◽  
Vol 57 (1-3) ◽  
pp. 239-243 ◽  
Author(s):  
Makoto Suzuki ◽  
Tomoko Okada ◽  
Takeo Taguchi ◽  
Yuji Hanzawa ◽  
Yoichi Iitaka
Keyword(s):  
Diels Alder ◽  
Electronic Effects ◽  
Furan Derivatives ◽  
Trifluoromethyl Groups

Influence of Trifluoromethyl Groups on the Crystal Packing of the Binuclear Copper(II) Complex Based on N2O3-Pentadentate (Hydroxy)bis(СF3-Enaminoketone)

2021 ◽  
Vol 47 (9) ◽  
pp. 631-637
Author(s):  
Yu. O. Edilova ◽  
Yu. S. Kudyakova ◽  
P. A. Slepukhin ◽  
Ya. V. Burgart ◽  
V. I. Saloutin ◽  
...  
Keyword(s):  
Crystal Packing ◽  
Binuclear Copper ◽  
Trifluoromethyl Groups
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