ChemInform Abstract: The Reductive Coupling of Tertiary Amides to Give Enediamines Using PhMe2SiLi.

ChemInform ◽  
2010 ◽  
Vol 29 (31) ◽  
pp. no-no ◽  
Author(s):  
I. FLEMING ◽  
U. GHOSH ◽  
S. R. MACK ◽  
B. P. CLARK
Keyword(s):  
Reductive Coupling ◽  
Tertiary Amides

Iridium‐Catalyzed Reductive Coupling of Grignard Reagents and Tertiary Amides

2020 ◽  
pp. 1-17
Author(s):  
Pablo Gabriel ◽  
Lan‐Gui Xie ◽  
Darren J. Dixon* ◽  
Karli R. Holman ◽  
Sarah E. Reisman
Keyword(s):  
Grignard Reagents ◽  
Reductive Coupling ◽  
Tertiary Amides

scholarly journals Tertiary amine synthesis via reductive coupling of amides with Grignard reagents

2017 ◽  
Vol 8 (11) ◽  
pp. 7492-7497 ◽  
Author(s):  
Lan-Gui Xie ◽  
Darren J. Dixon
Keyword(s):  
Tertiary Amine ◽  
Coupling Reaction ◽  
Grignard Reagents ◽  
Reductive Coupling ◽  
Tertiary Amides

A new iridium catalyzed reductive coupling reaction of Grignard reagents and tertiary amides affording functionalised tertiary amine products is described.

The reductive coupling of tertiary amides to give enediamines using PhMe2SiLi

1998 ◽  
pp. 711-712 ◽  
Author(s):  
Ian Fleming ◽  
Usha Ghosh ◽  
Stephen R. Mack ◽  
Ian Fleming ◽  
Usha Ghosh ◽  
...  
Keyword(s):  
Reductive Coupling ◽  
Tertiary Amides

Metal-free Reductive Coupling of Biphenyl Tosylhydrazones with Phenols or Benzyl Alcohols

2017 ◽  
Vol 14 (10) ◽  
Author(s):  
Yang Liu ◽  
Ping Liu ◽  
Yan Liu ◽  
Yu Wei ◽  
Bin Dai
Keyword(s):  
Reductive Coupling ◽  
Benzyl Alcohols ◽  
Metal Free

Photoreaction of N-butyl 3,4-dimethoxy-6-nitrobenzamide with butylamine. A model study for lysine-directed photoaffinity labelling

1987 ◽  
Vol 52 (7) ◽  
pp. 1780-1785 ◽  
Author(s):  
Petr Kuzmič ◽  
Libuše Pavlíčková ◽  
Milan Souček
Keyword(s):  
Nitro Group ◽  
Aromatic Ring ◽  
Ultraviolet Irradiation ◽  
Title Compound ◽  
Reductive Coupling ◽  
Photoaffinity Labelling ◽  
Photolysis Rate ◽  
Model Study ◽  
A Minor

Ultraviolet irradiation of the title compound I in the presence of butylamine gave predominantly products of nucleophilic photosubstitution by the amine, i.e., nitroanilines IIa and IIb. Besides, small amounts of products of hydrolysis (phenol III) and reductive coupling (azoxybenzene IV) were also formed. Comparison of the overall photolysis rate of I with that of 3,4-dimethoxy-1-nitrobenzene (V) indicates a minor loss of reactivity, most probably due to some deviation from coplanarity of the activating nitro group and the aromatic ring.

Direct reductive coupling of nitroarenes and alcohols catalysed by Co–N–C/CNT@AC

2019 ◽  
Vol 21 (8) ◽  
pp. 2129-2137 ◽  
Author(s):  
Di Liu ◽  
Ping Yang ◽  
Hao Zhang ◽  
Minjie Liu ◽  
Wenfei Zhang ◽  
...  
Keyword(s):  
Solvent Free ◽  
Reductive Coupling ◽  
Solvent Free Conditions

Imines and amines were synthesized on Co–N–C/CNT@AC by the coupling of nitroarenes and alcohols under base- and solvent-free conditions.

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