ChemInform Abstract: The Asymmetric Heck Reaction: Recent Developments and Applications of New Palladium Diphenylphosphinopyrrolidine Complexes

ChemInform ◽  
2010 ◽  
Vol 29 (28) ◽  
pp. no-no
Author(s):  
P. J. GUIRY ◽  
A. J. HENNESSY ◽  
J. P. CAHILL
Keyword(s):  
Heck Reaction ◽  
Asymmetric Heck Reaction ◽  
Recent Developments

Recent Developments in Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles

Synthesis ◽  
2020 ◽  
Author(s):  
Lili Shi ◽  
Junkai Fu ◽  
Shuangqiu Gao ◽  
Le Chang ◽  
Binglin Wang
Keyword(s):  
Heck Reaction ◽  
Alkyl Radicals ◽  
Type Reaction ◽  
The Past ◽  
Alkyl Electrophiles ◽  
Recent Developments ◽  
Palladium Catalyzed ◽  
Initial Work ◽  
Activated Olefins ◽  
Pseudo Halides

AbstractThe Mizoroki–Heck reaction is considered as one of the most ingenious and widely used methods for constructing C–C bonds. This reaction mainly focuses on activated olefins (styrenes, acrylates, or vinyl ethers) and aryl/vinyl (pseudo) halides. In comparison, the studies on unactivated alkenes and alkyl electrophiles are far less due to the low reactivity, poor selectivity, as well as competitive β-H elimination. In the past years, a growing interest has thus been devoted and significant breakthroughs have been achieved in the employment of unactivated alkenes and alkyl electrophiles as the reaction components, and this type of coupling is called as Heck-type or Heck-like reaction, which distinguishes from the traditional Heck reaction. Herein, we give a brief summary on Heck-type reaction between unactivated alkenes and alkyl electrophlies, covering its initial work, recent advancements, and mechanistic discussions.1 Introduction2 Intramolecular Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles2.1 Cobalt-Catalyzed Intramolecular Heck-Type Reaction2.2 Palladium-Catalyzed Intramolecular Heck-Type Reaction2.3 Nickel-Catalyzed Intramolecular Heck-Type Reaction2.4 Photocatalysis and Multimetallic Protocol for Intramolecular Heck-Type Reaction3 Intermolecular Heck-Type Reaction of Unactivated Alkenes and Alkyl Electrophiles3.1 Electrophilic Trifluoromethylating Reagent as Reaction Partners3.2 Alkyl Electrophiles as Reaction Partners4 Oxidative Heck-Type Reaction of Unactivated Alkenes and Alkyl Radicals5 Conclusions and Outlook

ChemInform Abstract: Highly Active Catalysts of Bisphosphine Oxides for Asymmetric Heck Reaction.

ChemInform ◽  
2014 ◽  
Vol 45 (6) ◽  
pp. no-no
Author(s):  
Jian Hu ◽  
Yunpeng Lu ◽  
Yongxin Li ◽  
Jianrong Zhou
Keyword(s):  
Heck Reaction ◽  
Highly Active ◽  
Asymmetric Heck Reaction

Asymmetric Heck Reaction: Catalytic Asymmetric Syntheses of Bicyclic Enones, Dienones and the Key Intermediate for Vernolepin

Synthesis ◽  
1993 ◽  
Vol 1993 (09) ◽  
pp. 920-930 ◽  
Author(s):  
Kazuhiro Kondo ◽  
Mikiko Sodeoka ◽  
Miwako Mori ◽  
Masakatsu Shibasaki
Keyword(s):  
Heck Reaction ◽  
Asymmetric Syntheses ◽  
Asymmetric Heck Reaction ◽  
Catalytic Asymmetric

The Synthesis of New HetPHOX Ligands and Their Application to the Intermolecular Asymmetric Heck Reaction

2009 ◽  
Vol 2009 (12) ◽  
pp. 1889-1895 ◽  
Author(s):  
Martin O. Fitzpatrick ◽  
Helge Muller-Bunz ◽  
Patrick J. Guiry
Keyword(s):  
Heck Reaction ◽  
Asymmetric Heck Reaction
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