ChemInform Abstract: Palladium-Catalyzed Cascade Reactions of Unsaturated Carbohydrate Derivatives. Synthesis of Enantiopure Tricyclic Compounds.

ChemInform ◽  
2010 ◽  
Vol 29 (9) ◽  
pp. no-no
Author(s):  
C. W. HOLZAPFEL ◽  
L. MARAIS
Keyword(s):  
Cascade Reactions ◽  
Tricyclic Compounds ◽  
Palladium Catalyzed

Palladium-Catalyzed Cascade Reactions of Isocyanides with Enaminones: Synthesis of 4-Aminoquinoline Derivatives

ACS Catalysis ◽  
2013 ◽  
Vol 4 (1) ◽  
pp. 49-52 ◽  
Author(s):  
Zheng-Yang Gu ◽  
Tong-Hao Zhu ◽  
Jia-Jia Cao ◽  
Xiao-Ping Xu ◽  
Shun-Yi Wang ◽  
...  
Keyword(s):  
Cascade Reactions ◽  
Palladium Catalyzed

Palladium-Catalyzed Molybdenum Hexacarbonyl-Mediated Gas-Free Carbonylative Reactions

Synlett ◽  
2018 ◽  
Vol 30 (02) ◽  
pp. 141-155 ◽  
Author(s):  
Luke Odell ◽  
Mats Larhed ◽  
Linda Åkerbladh
Keyword(s):  
Cascade Reactions ◽  
Ex Situ ◽  
Small Scale ◽  
Molybdenum Hexacarbonyl ◽  
Coupling Reactions ◽  
Problematic Use ◽  
Cross Coupling Reactions ◽  
Recent Developments ◽  
Palladium Catalyzed ◽  
Multistep Reactions

This account summarizes Pd(0)-catalyzed Mo(CO)6-mediated gas-free carbonylative reactions published in the period October 2011 to May 2018. Presented reactions include inter- and intramolecular carbonylations, carbonylative cross-couplings, and carbonylative multicomponent reactions using Mo(CO)6 as a solid source of CO. The presented methodologies were developed mainly for small-scale applications, avoiding the problematic use of gaseous CO in a standard laboratory. In most cases, the reported Mo(CO)6-mediated carbonylations were conducted in sealed vials or by using two-chamber solutions.1 Introduction2 Recent Developments2.1 New CO Sources2.2 Two-Chamber System for ex Situ CO Generation2.3 Multicomponent Carbonylations3 Carbonylations with N and O Nucleophiles4 Carbonylative Cross-Coupling Reactions with Organometallics5 Carbonylative Cascade Reactions6 Carbonylative Cascade, Multistep Reactions7 Summary and Outlook

Palladium-Catalyzed Cascade Reactions of δ-Ketonitriles with Arylboronic Acids: Synthesis of Pyridines

2020 ◽  
Vol 22 (3) ◽  
pp. 114-119 ◽  
Author(s):  
Xinrong Yao ◽  
Linjun Qi ◽  
Renhao Li ◽  
Qianqian Zhen ◽  
Jichao Liu ◽  
...  
Keyword(s):  
Cascade Reactions ◽  
Arylboronic Acids ◽  
Palladium Catalyzed

Development of an unexpected reaction pathway for the synthesis of 1,2,4-trisubstituted pyrrolo[1,2-a]quinoxalines through palladium-catalyzed cascade reactions

Tetrahedron ◽  
2017 ◽  
Vol 73 (12) ◽  
pp. 1633-1639 ◽  
Author(s):  
Ali Keivanloo ◽  
Atena Soozani ◽  
Mohammad Bakherad ◽  
Mahdi Mirzaee ◽  
Hadi Amiri Rudbari ◽  
...  
Keyword(s):  
Reaction Pathway ◽  
Cascade Reactions ◽  
Unexpected Reaction ◽  
Palladium Catalyzed

Correction to Palladium-Catalyzed Cascade Reactions of 1-(3-Arylprop-2-ynyloxy)-2-bromo Benzene Derivatives with Organoboron Compounds

2013 ◽  
Vol 78 (12) ◽  
pp. 6356-6356 ◽  
Author(s):  
Antonio Arcadi ◽  
Federico Blesi ◽  
Sandro Cacchi ◽  
Giancarlo Fabrizi ◽  
Antonella Goggiamani ◽  
...  
Keyword(s):  
Cascade Reactions ◽  
Benzene Derivatives ◽  
Organoboron Compounds ◽  
Palladium Catalyzed

scholarly journals Stereoselective synthesis of tricyclic compounds by intramolecular palladium-catalyzed addition of aryl iodides to carbonyl groups

2016 ◽  
Vol 12 ◽  
pp. 1236-1242 ◽  
Author(s):  
Jakub Saadi ◽  
Christoph Bentz ◽  
Kai Redies ◽  
Dieter Lentz ◽  
Reinhold Zimmer ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Stereoselective Synthesis ◽  
Carbonyl Groups ◽  
Relative Configuration ◽  
X Ray ◽  
Cyclization Process ◽  
Tricyclic Compounds ◽  
Methoxycarbonyl Group ◽  
Palladium Catalyzed ◽  
Group A

Starting from γ-ketoesters with an o-iodobenzyl group we studied a palladium-catalyzed cyclization process that stereoselectively led to bi- and tricyclic compounds in moderate to excellent yields. Four X-ray crystal structure analyses unequivocally defined the structure of crucial cyclization products. The relative configuration of the precursor compounds is essentially transferred to that of the products and the formed hydroxy group in the newly generated cyclohexane ring is consistently in trans-arrangement with respect to the methoxycarbonyl group. A transition-state model is proposed to explain the observed stereochemical outcome. This palladium-catalyzed Barbier-type reaction requires a reduction of palladium(II) back to palladium(0) which is apparently achieved by the present triethylamine.

ChemInform Abstract: Palladium-Catalyzed Cascade Reactions of 1-(3-Arylprop-2-ynyloxy)-2-bromo Benzene Derivatives with Organoboron Compounds.

ChemInform ◽  
2013 ◽  
Vol 44 (35) ◽  
pp. no-no
Author(s):  
Antonio Arcadi ◽  
Federico Blesi ◽  
Sandro Cacchi ◽  
Giancarlo Fabrizi ◽  
Antonella Goggiamani ◽  
...  
Keyword(s):  
Cascade Reactions ◽  
Benzene Derivatives ◽  
Organoboron Compounds ◽  
Palladium Catalyzed
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