ChemInform Abstract: Oxidation Products of C-4 and C-7 Hydroxyls in the Methyl α- Glycoside Derivatives of KDN.

ChemInform ◽  
2010 ◽  
Vol 28 (44) ◽  
pp. no-no
Author(s):  
T. KAI ◽  
X.-L. SUN ◽  
H. TAKAYANAGI ◽  
K. FURUHATA
2002 ◽  
Vol 55 (9) ◽  
pp. 807-813 ◽  
Author(s):  
Z. MANDIC ◽  
A. NARANDA ◽  
P. NOVAK ◽  
K. BRAJŠA ◽  
M. DEREK ◽  
...  

1997 ◽  
Vol 16 (4-5) ◽  
pp. 533-540 ◽  
Author(s):  
Toshitsugu Kai ◽  
Xue-Long Sun ◽  
Hiroaki Takayanagi ◽  
Kimio Furuhata

ChemInform ◽  
2003 ◽  
Vol 34 (10) ◽  
Author(s):  
Z. Mandic ◽  
A. Naranda ◽  
P. Noval ◽  
K. Brajsa ◽  
M. Derek ◽  
...  

1951 ◽  
Vol 29 (5) ◽  
pp. 398-408 ◽  
Author(s):  
R. H. Cox ◽  
E. Y. Spencer

Certain dehydration and oxidation products of cholesterol were prepared for subsequent animal experimentation. The ultraviolet absorption spectra of those derivatives possessing two or more conjugate chromophores were determined spectrophotometrically over the wave length range of 220 mμ to 350 mμ. The relative coincidence of the experimental λmax and εmax values of cholestadiene-3, 5 and of the enol acetate of cholesten–4–one–3 is offered as support for a 3, 5-diene structure for the latter steroid in particular and for enol esters of 4,5-unsaturated 3-ketosteroids in general.


Holzforschung ◽  
2003 ◽  
Vol 57 (5) ◽  
pp. 503-512 ◽  
Author(s):  
C. S. R. Freire ◽  
A. J. D. Silvestre ◽  
C. Pascoal Neto

Summary The structural changes of E. globulus wood extractives during bleaching with chlorine dioxide (D), oxygen (O), ozone (Z) and hydrogen peroxide (P) were studied. The detailed characterisation of the extractive derivatives detected in the partially bleached D, O, P and Z pulps was achieved by performing reactions of pure reference compounds with the different bleaching agents. The results show that the unsaturated sterols and fatty acids are extensively degraded during chlorine dioxide and ozone bleaching and only partially degraded during oxygen and hydrogen peroxide bleaching. The corresponding saturated extractives as well as the long chain aliphatic alcohols and ω-hydroxyfatty acids were stable during bleaching. The main oxidation products of β-sitosterol and oleic and linoleic acids, including one chlorinated derivative of linoleic acid, were identified here for the first time in E. globulus bleached pulps and bleaching filtrates.


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