ChemInform Abstract: Organomanganese Reagents. Part 35. Palladium-Catalyzed Selective Synthesis of Unsymmetrical Biaryls from Aryl Halides or Triflates and Organomanganese Reagents.

ChemInform ◽  
2010 ◽  
Vol 28 (38) ◽  
pp. no-no
Author(s):  
E. RIGUET ◽  
M. ALAMI ◽  
G. CAHIEZ
Keyword(s):  
Aryl Halides ◽  
Selective Synthesis ◽  
Palladium Catalyzed

Palladium-Catalyzed Ligand-Controlled Selective Synthesis of Aldehydes and Acids from Aryl Halides and Formic Acid

ChemCatChem ◽  
2017 ◽  
Vol 9 (16) ◽  
pp. 3121-3124 ◽  
Author(s):  
Fu-Peng Wu ◽  
Jin-Bao Peng ◽  
Ling-Shen Meng ◽  
Xinxin Qi ◽  
Xiao-Feng Wu
Keyword(s):  
Formic Acid ◽  
Aryl Halides ◽  
Selective Synthesis ◽  
Palladium Catalyzed

Direct and Selective Synthesis of Adipic and Other Dicarboxylic Acids by Palladium‐Catalyzed Carbonylation of Allylic Alcohols

2020 ◽  
Vol 59 (46) ◽  
pp. 20394-20398
Author(s):  
Ji Yang ◽  
Jiawang Liu ◽  
Yao Ge ◽  
Weiheng Huang ◽  
Helfried Neumann ◽  
...  
Keyword(s):  
Dicarboxylic Acids ◽  
Allylic Alcohols ◽  
Selective Synthesis ◽  
Palladium Catalyzed

scholarly journals Selective Synthesis of N-Acylnortropane Derivatives in Palladium-Catalysed Aminocarbonylation

Molecules ◽  
2021 ◽  
Vol 26 (6) ◽  
pp. 1813
Author(s):  
László Kollár ◽  
Ádám Erdélyi ◽  
Haroon Rasheed ◽  
Attila Takács
Keyword(s):  
Synthetic Method ◽  
Selective Synthesis ◽  
Varied Structure ◽  
Biological Importance ◽  
Aryl Iodides ◽  
Palladium Catalyzed ◽  
Derivatives Of

The aminocarbonylation of various alkenyl and (hetero)aryl iodides was carried out using tropane-based amines of biological importance, such as 8-azabicyclo[3.2.1]octan-3-one (nortropinone) and 3α-hydroxy-8-azabicyclo[3.2.1]octane (nortropine) as N-nucleophile. Using iodoalkenes, the two nucleophiles were selectively converted to the corresponding amide in the presence of Pd(OAc)2/2 PPh3 catalysts. In the presence of several iodo(hetero)arenes, the application of the bidentate Xantphos was necessary to produce the target compounds selectively. The new carboxamides of varied structure, formed in palladium-catalyzed aminocarbonylation reactions, were isolated and fully characterized. In this way, a novel synthetic method has been developed for the producing of N-acylnortropane derivatives of biological importance.

Palladium Catalyzed Cascade Azidation/Carbonylation of Aryl Halides with Sodium Azide for the Synthesis of Amides

2021 ◽  
Author(s):  
Zhuang Qi ◽  
Shan‐Shan Li ◽  
Lin Li ◽  
Qi Qin ◽  
Li‐Miao Yang ◽  
...  
Keyword(s):  
Sodium Azide ◽  
Aryl Halides ◽  
Palladium Catalyzed
Sign in / Sign up

Export Citation Format

Share Document