ChemInform Abstract: Solid-Acid-Catalyzed Alkane Cracking Mechanisms: Evidence from Reactions of Small Probe Molecules

ChemInform ◽  
2010 ◽  
Vol 28 (29) ◽  
pp. no-no
Author(s):  
F. C. JENTOFT ◽  
B. C. GATES
Keyword(s):  
Solid Acid ◽  
Probe Molecules ◽  
Small Probe ◽  
Cracking Mechanisms ◽  
Acid Catalyzed ◽  
Alkane Cracking

scholarly journals Hierarchical HZSM-5 for Catalytic Cracking of Oleic Acid to Biofuels

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 747
Author(s):  
Mahashanon Arumugam ◽  
Chee Keong Goh ◽  
Zulkarnain Zainal ◽  
Sugeng Triwahyono ◽  
Adam F. Lee ◽  
...  
Keyword(s):  
Oleic Acid ◽  
Solid Acid ◽  
High Surface ◽  
High Surface Area ◽  
Acid Catalyst ◽  
Hierarchical Network ◽  
Waste Oil ◽  
Acid Catalyzed ◽  
Zeolite Seeds ◽  
20 Nm

Solid acid catalyzed cracking of waste oil-derived fatty acids is an attractive route to hydrocarbon fuels. HZSM-5 is an effective acid catalyst for fatty acid cracking; however, its microporous nature is susceptible to rapid deactivation by coking. We report the synthesis and application of hierarchical HZSM-5 (h-HZSM-5) in which silanization of pre-crystallized zeolite seeds is employed to introduce mesoporosity during the aggregation of growing crystallites. The resulting h-HZSM-5 comprises a disordered array of fused 10–20 nm crystallites and mesopores with a mean diameter of 13 nm, which maintain the high surface area and acidity of a conventional HZSM-5. Mesopores increase the yield of diesel range hydrocarbons obtained from oleic acid deoxygenation from ~20% to 65%, attributed to improved acid site accessibility within the hierarchical network.

Small Mesh Size Hydrogel for Functional Photocontrol of Encapsulated Enzymes and Small Probe Molecules

2012 ◽  
Vol 84 (3) ◽  
pp. 1374-1379 ◽  
Author(s):  
Shuhei Murayama ◽  
Fumi Ishizuka ◽  
Kaihei Takagi ◽  
Hirotaka Inoda ◽  
Akira Sano ◽  
...  
Keyword(s):  
Mesh Size ◽  
Probe Molecules ◽  
Small Probe

Solid acid catalyzed biodiesel production by simultaneous esterification and transesterification

2006 ◽  
Vol 8 (12) ◽  
pp. 1056 ◽  
Author(s):  
Mangesh G. Kulkarni ◽  
Rajesh Gopinath ◽  
Lekha Charan Meher ◽  
Ajay Kumar Dalai
Keyword(s):  
Solid Acid ◽  
Biodiesel Production ◽  
Acid Catalyzed

scholarly journals Biomass‐Derived Aromatics by Solid Acid‐Catalyzed Aldol Condensation of Alkyl Methyl Ketones

2020 ◽  
Vol 4 (10) ◽  
pp. 1900150
Author(s):  
Phillip Reif ◽  
Hannah Rosenthal ◽  
Marcus Rose
Keyword(s):  
Solid Acid ◽  
Aldol Condensation ◽  
Methyl Ketones ◽  
Acid Catalyzed

Solid acid catalyzed synthesis of furans from carbohydrates

2016 ◽  
Vol 58 (1) ◽  
pp. 36-112 ◽  
Author(s):  
Prasenjit Bhaumik ◽  
Paresh Laxmikant Dhepe
Keyword(s):  
Solid Acid ◽  
Acid Catalyzed

Cellulose pretreatment with 1-n-butyl-3-methylimidazolium chloride for solid acid-catalyzed hydrolysis

2010 ◽  
Vol 101 (21) ◽  
pp. 8273-8279 ◽  
Author(s):  
Soo-Jin Kim ◽  
Adid Adep Dwiatmoko ◽  
Jae Wook Choi ◽  
Young-Woong Suh ◽  
Dong Jin Suh ◽  
...  
Keyword(s):  
Solid Acid ◽  
Acid Catalyzed
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