ChemInform Abstract: A Novel Chiral Phosphinediamine Ligand and Asymmetric Hydrogenation of Acrylic Acid Derivatives.

ChemInform ◽  
2010 ◽  
Vol 28 (14) ◽  
pp. no-no
Author(s):  
I. YAMADA ◽  
M. YAMAGUCHI ◽  
T. YAMAGISHI
Keyword(s):  
Acrylic Acid ◽  
Asymmetric Hydrogenation

A novel chiral phosphinediamine ligand and asymmetric hydrogenation of acrylic acid derivatives

1996 ◽  
Vol 7 (12) ◽  
pp. 3339-3342 ◽  
Author(s):  
Issaku Yamada ◽  
Motowo Yamaguchi ◽  
Takamichi Yamagishi
Keyword(s):  
Acrylic Acid ◽  
Asymmetric Hydrogenation

The Synthesis of Amphiphilic Chiral Dendritic 1,1′-Bi-2-Naphthol Derivatives and their Application as Amphiphiles in Aqueous Asymmetric Hydrogenation

2002 ◽  
Vol 2002 (7) ◽  
pp. 318-320 ◽  
Author(s):  
Qing-Hua Fan ◽  
Rui Zhang ◽  
Guo-Jun Deng ◽  
Xiao-Min Chen
Keyword(s):  
Acrylic Acid ◽  
Aqueous Media ◽  
Asymmetric Hydrogenation ◽  
Optically Active ◽  
Coupling Reactions ◽  
Aryl Ether ◽  
Naphthol Derivatives

Six new amphiphilic chiral dendritic BINOLs were synthesised via coupling reactions of optically active BINOL and the Frèchet-type poly(aryl ether) dendrons with peripheral oligo(ethyleneglycol) groups, and were used as amphiphiles for promoting the asymmetric hydrogenation of 2-[p-(2-methylpropyl)- phenyl]acrylic acid in an aqueous media.

Soft ionic liquid based resistive memory characteristics in a two terminal discrete polydimethylsiloxane cylindrical microchannel

2020 ◽  
Vol 8 (38) ◽  
pp. 13368-13374
Author(s):  
Muhammad Umair Khan ◽  
Gul Hassan ◽  
Jinho Bae
Keyword(s):  
Ionic Liquid ◽  
Acrylic Acid ◽  
Sodium Hydroxide ◽  
Sodium Salt ◽  
Resistive Memory ◽  
Cylindrical Microchannel ◽  
Memory Characteristics ◽  
Poly Acrylic Acid

This paper proposes a novel soft ionic liquid (IL) electrically functional device that displays resistive memory characteristics using poly(acrylic acid) partial sodium salt (PAA-Na+:H2O) solution gel and sodium hydroxide (NaOH) in a thin polydimethylsiloxane (PDMS) cylindrical microchannel.

The Role of the Initiator System in the Synthesis of Acidic Multifunctional Nanoparticles Designed for Molecular Imprinting of Proteins

2020 ◽  
Vol 65 (1) ◽  
pp. 28-41
Author(s):  
Marwa Aly Ahmed ◽  
Júlia Erdőssy ◽  
Viola Horváth
Keyword(s):  
Acrylic Acid ◽  
Binding Affinity ◽  
Molecular Imprinting ◽  
Low Temperatures ◽  
Ammonium Persulfate ◽  
Sodium Bisulfite ◽  
Multifunctional Nanoparticles ◽  
High Affinity ◽  
Initiator System

Multifunctional nanoparticles have been shown earlier to bind certain proteins with high affinity and the binding affinity could be enhanced by molecular imprinting of the target protein. In this work different initiator systems were used and compared during the synthesis of poly (N-isopropylacrylamide-co-acrylic acid-co-N-tert-butylacrylamide) nanoparticles with respect to their future applicability in molecular imprinting of lysozyme. The decomposition of ammonium persulfate initiator was initiated either thermally at 60 °C or by using redox activators, namely tetramethylethylenediamine or sodium bisulfite at low temperatures. Morphology differences in the resulting nanoparticles have been revealed using scanning electron microscopy and dynamic light scattering. During polymerization the conversion of each monomer was followed in time. Striking differences were demonstrated in the incorporation rate of acrylic acid between the tetramethylethylenediamine catalyzed initiation and the other systems. This led to a completely different nanoparticle microstructure the consequence of which was the distinctly lower lysozyme binding affinity. On the contrary, the use of sodium bisulfite activation resulted in similar nanoparticle structural homogeneity and protein binding affinity as the thermal initiation.

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